Highly filled polystyrene–laponite nanocomposites prepared by emulsion polymerization
Polystyrene-based nanocomposite films containing up to 20 wt% laponite clay have been prepared by emulsion polymerization. Significant increases in the storage and tensile moduli were observed in both the glassy and rubbery state on laponite addition. However, whereas in the glassy state these incre...
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| Veröffentlicht in: | European polymer journal 2009-03, Vol.45 (3), p.621-629 |
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| container_title | European polymer journal |
| container_volume | 45 |
| creator | Ruggerone, Riccardo Plummer, Christopher J.G. Herrera, Norma Negrete Bourgeat-Lami, Elodie Månson, Jan-Anders E. |
| description | Polystyrene-based nanocomposite films containing up to 20
wt% laponite clay have been prepared by emulsion polymerization. Significant increases in the storage and tensile moduli were observed in both the glassy and rubbery state on laponite addition. However, whereas in the glassy state these increases were correlated with the extent of exfoliation of the laponite, in the rubbery state they were more dependent on the overall laponite content. These results are discussed in terms of the observed morphologies and micromechanical models for the reinforcing effect of rigid nano-sized filler particles. |
| doi_str_mv | 10.1016/j.eurpolymj.2008.12.032 |
| format | Article |
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| ispartof | European polymer journal, 2009-03, Vol.45 (3), p.621-629 |
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| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00724904v1 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Chemical Sciences Composites Emulsion polymerization Exact sciences and technology Forms of application and semi-finished materials Laponite Mechanical properties Nanocomposites Polymer industry, paints, wood Polymers Polystyrene Technology of polymers |
| title | Highly filled polystyrene–laponite nanocomposites prepared by emulsion polymerization |
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