Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina
The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in th...
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| Veröffentlicht in: | Catalysis today 2011, Vol.164 (1), p.28-33 |
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| container_title | Catalysis today |
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| creator | Pattamakomsan, Kanda Ehret, Eric Morfin, Franck Gélin, Patrick Jugnet, Yvette Prakash, Swamny Bertolini, Jean Claude Panpranot, Joongjai Aires, Francisco José Cadete Santos |
| description | The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in the selective hydrogenation of 1,3-butadiene was achieved over Pd–Sn on the mixed phase alumina support in which butane formation and isomerization of 1-butene were suppressed. Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion. |
| doi_str_mv | 10.1016/j.cattod.2010.10.013 |
| format | Article |
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The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in the selective hydrogenation of 1,3-butadiene was achieved over Pd–Sn on the mixed phase alumina support in which butane formation and isomerization of 1-butene were suppressed. Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion.</description><identifier>ISSN: 0920-5861</identifier><identifier>EISSN: 1873-4308</identifier><identifier>DOI: 10.1016/j.cattod.2010.10.013</identifier><identifier>CODEN: CATTEA</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>1,3-Butadiene hydrogenation ; aluminum oxide ; Catalysis ; catalysts ; catalytic activity ; Chemical Sciences ; Chemistry ; Environment and Society ; Environmental Sciences ; Exact sciences and technology ; Fourier transform infrared spectroscopy ; General and physical chemistry ; hydrogenation ; isomerization ; Mixed phase alumina ; Pd/Al 2O 3 ; Pd–Sn/Al 2O 3 ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Catalysis today, 2011, Vol.164 (1), p.28-33</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c431t-2ed6cc7f5b9d1a505d146f766c7682113ae53efc6f82bc2776d399fa608b22c83</citedby><cites>FETCH-LOGICAL-c431t-2ed6cc7f5b9d1a505d146f766c7682113ae53efc6f82bc2776d399fa608b22c83</cites><orcidid>0000-0003-4617-0227 ; 0000-0003-3272-708X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.cattod.2010.10.013$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,309,310,314,780,784,789,790,885,3550,4024,4050,4051,23930,23931,25140,27923,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24200225$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00699707$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Pattamakomsan, Kanda</creatorcontrib><creatorcontrib>Ehret, Eric</creatorcontrib><creatorcontrib>Morfin, Franck</creatorcontrib><creatorcontrib>Gélin, Patrick</creatorcontrib><creatorcontrib>Jugnet, Yvette</creatorcontrib><creatorcontrib>Prakash, Swamny</creatorcontrib><creatorcontrib>Bertolini, Jean Claude</creatorcontrib><creatorcontrib>Panpranot, Joongjai</creatorcontrib><creatorcontrib>Aires, Francisco José Cadete Santos</creatorcontrib><title>Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina</title><title>Catalysis today</title><description>The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in the selective hydrogenation of 1,3-butadiene was achieved over Pd–Sn on the mixed phase alumina support in which butane formation and isomerization of 1-butene were suppressed. Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion.</description><subject>1,3-Butadiene hydrogenation</subject><subject>aluminum oxide</subject><subject>Catalysis</subject><subject>catalysts</subject><subject>catalytic activity</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Environment and Society</subject><subject>Environmental Sciences</subject><subject>Exact sciences and technology</subject><subject>Fourier transform infrared spectroscopy</subject><subject>General and physical chemistry</subject><subject>hydrogenation</subject><subject>isomerization</subject><subject>Mixed phase alumina</subject><subject>Pd/Al 2O 3</subject><subject>Pd–Sn/Al 2O 3</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pattamakomsan, Kanda</creatorcontrib><creatorcontrib>Ehret, Eric</creatorcontrib><creatorcontrib>Morfin, Franck</creatorcontrib><creatorcontrib>Gélin, Patrick</creatorcontrib><creatorcontrib>Jugnet, Yvette</creatorcontrib><creatorcontrib>Prakash, Swamny</creatorcontrib><creatorcontrib>Bertolini, Jean Claude</creatorcontrib><creatorcontrib>Panpranot, Joongjai</creatorcontrib><creatorcontrib>Aires, Francisco José Cadete Santos</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Catalysis today</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pattamakomsan, Kanda</au><au>Ehret, Eric</au><au>Morfin, Franck</au><au>Gélin, Patrick</au><au>Jugnet, Yvette</au><au>Prakash, Swamny</au><au>Bertolini, Jean Claude</au><au>Panpranot, Joongjai</au><au>Aires, Francisco José Cadete Santos</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina</atitle><jtitle>Catalysis today</jtitle><date>2011</date><risdate>2011</risdate><volume>164</volume><issue>1</issue><spage>28</spage><epage>33</epage><pages>28-33</pages><issn>0920-5861</issn><eissn>1873-4308</eissn><coden>CATTEA</coden><abstract>The gas phase selective hydrogenation of 1,3-butadiene was studied over Pd and Pd–Sn supported on mixed phase θ/α-(MA) and pure α-alumina (AA). The catalysts were characterized by XRD, XPS, TEM, and FTIR spectroscopy of adsorbed CO. A remarkable improvement in terms of activity and selectivity in the selective hydrogenation of 1,3-butadiene was achieved over Pd–Sn on the mixed phase alumina support in which butane formation and isomerization of 1-butene were suppressed. Nevertheless, Pd–Sn/AA showed much lower activity than Pd–Sn/MA due to lower metal dispersion.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.cattod.2010.10.013</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-4617-0227</orcidid><orcidid>https://orcid.org/0000-0003-3272-708X</orcidid></addata></record> |
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| subjects | 1,3-Butadiene hydrogenation aluminum oxide Catalysis catalysts catalytic activity Chemical Sciences Chemistry Environment and Society Environmental Sciences Exact sciences and technology Fourier transform infrared spectroscopy General and physical chemistry hydrogenation isomerization Mixed phase alumina Pd/Al 2O 3 Pd–Sn/Al 2O 3 Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina |
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