Allylic ruthenium(IV) complexes in catalysis
Two types of allylic ruthenium(IV) complexes. Two families of ruthenium catalysts with wide applications. [Display omitted] ► Applications of bis(allyl)ruthenium(IV) complexes in various catalytic transformations. ► (Allyl)ruthenium(IV) catalysts for allylation of nucleophiles. ► Miscellaneous react...
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| Veröffentlicht in: | Coordination chemistry reviews 2012-03, Vol.256 (5-8), p.525-536 |
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| creator | Bruneau, Christian Achard, Mathieu |
| description | Two types of allylic ruthenium(IV) complexes. Two families of ruthenium catalysts with wide applications. [Display omitted]
► Applications of bis(allyl)ruthenium(IV) complexes in various catalytic transformations. ► (Allyl)ruthenium(IV) catalysts for allylation of nucleophiles. ► Miscellaneous reactions involving allylic ruthenium(IV) species.
This review presents recent advances in the use of allylic ruthenium(IV) complexes as precatalysts in transition metal-catalyzed reactions. The topic is dominated by nucleophilic substitution reactions, where they appear either as initial catalysts or are generated upon oxidative addition of allylic substrates to ruthenium(II) precatalysts. Indeed, the general catalytic cycle describing this reaction is based on Ru(II)/Ru(IV) alternance. Other applications of allylic complexes, especially bis(allyl)Ru(IV) complexes in various catalytic transformations are also reported. |
| doi_str_mv | 10.1016/j.ccr.2011.10.018 |
| format | Article |
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► Applications of bis(allyl)ruthenium(IV) complexes in various catalytic transformations. ► (Allyl)ruthenium(IV) catalysts for allylation of nucleophiles. ► Miscellaneous reactions involving allylic ruthenium(IV) species.
This review presents recent advances in the use of allylic ruthenium(IV) complexes as precatalysts in transition metal-catalyzed reactions. The topic is dominated by nucleophilic substitution reactions, where they appear either as initial catalysts or are generated upon oxidative addition of allylic substrates to ruthenium(II) precatalysts. Indeed, the general catalytic cycle describing this reaction is based on Ru(II)/Ru(IV) alternance. Other applications of allylic complexes, especially bis(allyl)Ru(IV) complexes in various catalytic transformations are also reported.</description><identifier>ISSN: 0010-8545</identifier><identifier>EISSN: 1873-3840</identifier><identifier>EISSN: 0010-8545</identifier><identifier>DOI: 10.1016/j.ccr.2011.10.018</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Allylation ; Catalysis ; Chemical Sciences ; Homogeneous catalysis ; Ruthenium allyl species ; Ruthenium(IV)</subject><ispartof>Coordination chemistry reviews, 2012-03, Vol.256 (5-8), p.525-536</ispartof><rights>2011 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c397t-fe59e9d1492ec6e1eb60d4fb5f16284d6275bcd0195f90ee9872ba322fd4d8c13</citedby><cites>FETCH-LOGICAL-c397t-fe59e9d1492ec6e1eb60d4fb5f16284d6275bcd0195f90ee9872ba322fd4d8c13</cites><orcidid>0000-0003-0578-9680 ; 0000-0002-2220-1458</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ccr.2011.10.018$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00697889$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Bruneau, Christian</creatorcontrib><creatorcontrib>Achard, Mathieu</creatorcontrib><title>Allylic ruthenium(IV) complexes in catalysis</title><title>Coordination chemistry reviews</title><description>Two types of allylic ruthenium(IV) complexes. Two families of ruthenium catalysts with wide applications. [Display omitted]
► Applications of bis(allyl)ruthenium(IV) complexes in various catalytic transformations. ► (Allyl)ruthenium(IV) catalysts for allylation of nucleophiles. ► Miscellaneous reactions involving allylic ruthenium(IV) species.
This review presents recent advances in the use of allylic ruthenium(IV) complexes as precatalysts in transition metal-catalyzed reactions. The topic is dominated by nucleophilic substitution reactions, where they appear either as initial catalysts or are generated upon oxidative addition of allylic substrates to ruthenium(II) precatalysts. Indeed, the general catalytic cycle describing this reaction is based on Ru(II)/Ru(IV) alternance. Other applications of allylic complexes, especially bis(allyl)Ru(IV) complexes in various catalytic transformations are also reported.</description><subject>Allylation</subject><subject>Catalysis</subject><subject>Chemical Sciences</subject><subject>Homogeneous catalysis</subject><subject>Ruthenium allyl species</subject><subject>Ruthenium(IV)</subject><issn>0010-8545</issn><issn>1873-3840</issn><issn>0010-8545</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLwzAUx4MoOKcfwFuPDmzNS9s0wVMZ6gYDL-o1pMkry8jWkXTDfXtbJh49Pf6P_-_B-xFyDzQDCvxpkxkTMkYBhpxREBdkAqLK01wU9JJMKAWairIor8lNjJshcinZhDzW3p-8M0k49GvcucP2Yfk1S0y33Xv8xpi4XWJ0r_0punhLrlrtI979zin5fH35mC_S1fvbcl6vUpPLqk9bLCVKC4VkaDgCNpzaom3KFjgTheWsKhtjKciylRRRioo1OmestYUVBvIpmZ3vrrVX--C2OpxUp51a1Cs17ijlshJCHscunLsmdDEGbP8AoGpUozZqUKNGNeNqUDMwz2cGhyeODoOKxuHOoHUBTa9s5_6hfwBSdmqa</recordid><startdate>20120301</startdate><enddate>20120301</enddate><creator>Bruneau, Christian</creator><creator>Achard, Mathieu</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-0578-9680</orcidid><orcidid>https://orcid.org/0000-0002-2220-1458</orcidid></search><sort><creationdate>20120301</creationdate><title>Allylic ruthenium(IV) complexes in catalysis</title><author>Bruneau, Christian ; Achard, Mathieu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c397t-fe59e9d1492ec6e1eb60d4fb5f16284d6275bcd0195f90ee9872ba322fd4d8c13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Allylation</topic><topic>Catalysis</topic><topic>Chemical Sciences</topic><topic>Homogeneous catalysis</topic><topic>Ruthenium allyl species</topic><topic>Ruthenium(IV)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bruneau, Christian</creatorcontrib><creatorcontrib>Achard, Mathieu</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Coordination chemistry reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bruneau, Christian</au><au>Achard, Mathieu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Allylic ruthenium(IV) complexes in catalysis</atitle><jtitle>Coordination chemistry reviews</jtitle><date>2012-03-01</date><risdate>2012</risdate><volume>256</volume><issue>5-8</issue><spage>525</spage><epage>536</epage><pages>525-536</pages><issn>0010-8545</issn><eissn>1873-3840</eissn><eissn>0010-8545</eissn><abstract>Two types of allylic ruthenium(IV) complexes. Two families of ruthenium catalysts with wide applications. [Display omitted]
► Applications of bis(allyl)ruthenium(IV) complexes in various catalytic transformations. ► (Allyl)ruthenium(IV) catalysts for allylation of nucleophiles. ► Miscellaneous reactions involving allylic ruthenium(IV) species.
This review presents recent advances in the use of allylic ruthenium(IV) complexes as precatalysts in transition metal-catalyzed reactions. The topic is dominated by nucleophilic substitution reactions, where they appear either as initial catalysts or are generated upon oxidative addition of allylic substrates to ruthenium(II) precatalysts. Indeed, the general catalytic cycle describing this reaction is based on Ru(II)/Ru(IV) alternance. Other applications of allylic complexes, especially bis(allyl)Ru(IV) complexes in various catalytic transformations are also reported.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.ccr.2011.10.018</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-0578-9680</orcidid><orcidid>https://orcid.org/0000-0002-2220-1458</orcidid></addata></record> |
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| subjects | Allylation Catalysis Chemical Sciences Homogeneous catalysis Ruthenium allyl species Ruthenium(IV) |
| title | Allylic ruthenium(IV) complexes in catalysis |
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