Mixed monolayers of cationic surfactants and anionic polymers at the air-water interface : Surface tension and ellipsometry studies
Equilibrium surface tension measurements have been carried out on mixed solutions of a non-surface active polyelectrolyte (polyacrylamide sulfonate) and cationic surfactants. A strong synergistic lowering of the surface tension is found in the concentration range where no appreciable complexation of...
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| Veröffentlicht in: | The European physical journal. B, Condensed matter physics Condensed matter physics, 1998, Vol.5 (4), p.905-911 |
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| container_title | The European physical journal. B, Condensed matter physics |
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| creator | ASNACIOS, A LANGEVIN, D ARGILLIER, J. F |
| description | Equilibrium surface tension measurements have been carried out on mixed solutions of a non-surface active polyelectrolyte (polyacrylamide sulfonate) and cationic surfactants. A strong synergistic lowering of the surface tension is found in the concentration range where no appreciable complexation of surfactant and polymer occurs in the bulk solution (as seen from viscosity measurements). The surface tension decrease does not depend upon the polymer molecular weight, and there is a limited influence of the surfactant chain length. The influence of the degree of charge of the polymer is more important: for small degree of charge, the complexation is less cooperative, and the structure of the surface complex is looser. |
| doi_str_mv | 10.1007/s100510050516 |
| format | Article |
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| ispartof | The European physical journal. B, Condensed matter physics, 1998, Vol.5 (4), p.905-911 |
| issn | 1434-6028 1434-6036 |
| language | eng |
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| source | SpringerNature Journals |
| subjects | Applied sciences Classical Physics Exact sciences and technology Organic polymers Physicochemistry of polymers Physics Properties and characterization Surface properties |
| title | Mixed monolayers of cationic surfactants and anionic polymers at the air-water interface : Surface tension and ellipsometry studies |
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