Competitive adsorption of surfactants at air/water interfaces
The zeta potential of an air bubble suspended in an aqueous solution of mixed fluorocarbon and hydrocarbon anionic surfactants is studied over a wide range of concentrations and mixture compositions. The zeta potential is related to surfactant ion adsorption. The two surfactants, which exhibit an an...
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| Veröffentlicht in: | Journal of colloid and interface science 2003-05, Vol.261 (2), p.233-237 |
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| container_end_page | 237 |
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| container_title | Journal of colloid and interface science |
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| creator | Graciaa, A Creux, P Lachaise, J Schechter, R.S |
| description | The zeta potential of an air bubble suspended in an aqueous solution of mixed fluorocarbon and hydrocarbon anionic surfactants is studied over a wide range of concentrations and mixture compositions. The zeta potential is related to surfactant ion adsorption. The two surfactants, which exhibit an antipathy manifested by micellar demixing, compete for surface sites. The total surfactant adsorption is reduced when both surfactants are present. Adsorption phenomena are closely correlated to the micellar phase diagram. |
| doi_str_mv | 10.1016/S0021-9797(03)00052-3 |
| format | Article |
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The zeta potential is related to surfactant ion adsorption. The two surfactants, which exhibit an antipathy manifested by micellar demixing, compete for surface sites. The total surfactant adsorption is reduced when both surfactants are present. 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Adsorption phenomena are closely correlated to the micellar phase diagram.</description><subject>Air/water interfaces</subject><subject>Chemical Physics</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Gas-liquid interface and liquid-liquid interface</subject><subject>General and physical chemistry</subject><subject>Mixed surfactants</subject><subject>Physics</subject><subject>Surface physical chemistry</subject><subject>Surfactant adsorption</subject><subject>Zeta potential</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkE1PGzEQhq0KVALtT2i1Fyo4LIzttXd9qCoU8SVF4tD2bHntsTDarFPbCeLfd0MiOHKxpfHzzowfQr5RuKBA5eVvAEZr1ar2DPg5AAhW809kRkGJuqXAD8jsDTkixzk_AVAqhPpMjqhkQgrWzsjPeVyusIQSNlgZl2NalRDHKvoqr5M3tpix5MqUyoR0-WwKpiqM0zk9Yf5CDr0ZMn7d3yfk7831n_ldvXi4vZ9fLWrbMFFq2jSUd8LIljs5lXzXKeu5YK53QqL1vfIOve0bAdYq75UzjGMvEBuuUPETcr7r-2gGvUphadKLjibou6uF3tYApKKM0Q2d2B87dpXivzXmopchWxwGM2JcZ91SCV3D2QSKHWhTzDmhf-tMQW8d61fHeitQA9evjjWfct_3A9b9Et17ai91Ak73gMnWDD6Z0Yb8zjVtJ6Ta_urXjsNJ3SZg0tkGHC26kNAW7WL4YJX_AJ6YXQ</recordid><startdate>20030515</startdate><enddate>20030515</enddate><creator>Graciaa, A</creator><creator>Creux, P</creator><creator>Lachaise, J</creator><creator>Schechter, R.S</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-7331-4092</orcidid></search><sort><creationdate>20030515</creationdate><title>Competitive adsorption of surfactants at air/water interfaces</title><author>Graciaa, A ; Creux, P ; Lachaise, J ; Schechter, R.S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c425t-1441385a673d6c42f889cf352dbd56ecfb9fdefcb450cc9ff9da23eb5ee439e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Air/water interfaces</topic><topic>Chemical Physics</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Gas-liquid interface and liquid-liquid interface</topic><topic>General and physical chemistry</topic><topic>Mixed surfactants</topic><topic>Physics</topic><topic>Surface physical chemistry</topic><topic>Surfactant adsorption</topic><topic>Zeta potential</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Graciaa, A</creatorcontrib><creatorcontrib>Creux, P</creatorcontrib><creatorcontrib>Lachaise, J</creatorcontrib><creatorcontrib>Schechter, R.S</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Graciaa, A</au><au>Creux, P</au><au>Lachaise, J</au><au>Schechter, R.S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Competitive adsorption of surfactants at air/water interfaces</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2003-05-15</date><risdate>2003</risdate><volume>261</volume><issue>2</issue><spage>233</spage><epage>237</epage><pages>233-237</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>The zeta potential of an air bubble suspended in an aqueous solution of mixed fluorocarbon and hydrocarbon anionic surfactants is studied over a wide range of concentrations and mixture compositions. 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| ispartof | Journal of colloid and interface science, 2003-05, Vol.261 (2), p.233-237 |
| issn | 0021-9797 1095-7103 |
| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Air/water interfaces Chemical Physics Chemistry Exact sciences and technology Gas-liquid interface and liquid-liquid interface General and physical chemistry Mixed surfactants Physics Surface physical chemistry Surfactant adsorption Zeta potential |
| title | Competitive adsorption of surfactants at air/water interfaces |
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