Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization

Four different xanthates containing either phosphonate or bisphosphonate moieties were synthesized with high degree of purity. These xanthates were used as chain transfer agents (CTA) in the RAFT/MADIX polymerization of vinyl acetate (VAc) to prepare end‐capped poly(VAc). The rate of VAc polymerizat...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2012-05, Vol.50 (10), p.1997-2007
Hauptverfasser:	Dufils, P-E., David, G., Boutevin, B., Woodward, G., Otter, G., Guinaudeau, A., Mazières, S., Destarac, M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetates Applied sciences bisphosphonate Chain transfer Chemical Sciences Conversion Exact sciences and technology heteroatom-containing polymers kinetics Mathematical analysis Monomers Organic polymers Physicochemistry of polymers poly(vinyl acetate) Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts RAFT/MADIX macromolecular design by interchange of xanthates (RAFT/MADIX) Rafts reversible addition-fragmentation chain transfer polymerization (RAFT) Vinyl acetate xanthate
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