Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization
Four different xanthates containing either phosphonate or bisphosphonate moieties were synthesized with high degree of purity. These xanthates were used as chain transfer agents (CTA) in the RAFT/MADIX polymerization of vinyl acetate (VAc) to prepare end‐capped poly(VAc). The rate of VAc polymerizat...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2012-05, Vol.50 (10), p.1997-2007 |
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| container_issue | 10 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
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| creator | Dufils, P-E. David, G. Boutevin, B. Woodward, G. Otter, G. Guinaudeau, A. Mazières, S. Destarac, M. |
| description | Four different xanthates containing either phosphonate or bisphosphonate moieties were synthesized with high degree of purity. These xanthates were used as chain transfer agents (CTA) in the RAFT/MADIX polymerization of vinyl acetate (VAc) to prepare end‐capped poly(VAc). The rate of VAc polymerization in the presence of these new CTAs was shown to be similar to that obtained with conventional xanthate, that is, (methyl ethoxycarbonothioyl) sulfanyl acetate. Good control of VAc polymerization was also obtained since the molecular weight increased linearly with monomer conversion for each phosphonate‐containing xanthate. Low‐PDI values were obtained, ascribed to efficient exchange during RAFT/MADIX polymerization. Cex value was therefore calculated to about 25, based on RAFT/MADIX of VAc in the presence of rhodixan A1/VAc adduct. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
A new series of phosphonate/bisphosphonate‐containing xanthates was efficiently synthesized and used as chain transfer agents in the RAFT/MADIX polymerization of VAc. Very good control of the VAc polymerization was obtained for each xanthate, thus leading to PVAc end‐capped with either phosphonate or bisphosphonate moieties. |
| doi_str_mv | 10.1002/pola.25974 |
| format | Article |
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A new series of phosphonate/bisphosphonate‐containing xanthates was efficiently synthesized and used as chain transfer agents in the RAFT/MADIX polymerization of VAc. Very good control of the VAc polymerization was obtained for each xanthate, thus leading to PVAc end‐capped with either phosphonate or bisphosphonate moieties.</description><identifier>ISSN: 0887-624X</identifier><identifier>ISSN: 0449-296X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>EISSN: 1542-9350</identifier><identifier>DOI: 10.1002/pola.25974</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Acetates ; Applied sciences ; bisphosphonate ; Chain transfer ; Chemical Sciences ; Conversion ; Exact sciences and technology ; heteroatom-containing polymers ; kinetics ; Mathematical analysis ; Monomers ; Organic polymers ; Physicochemistry of polymers ; poly(vinyl acetate) ; Polymerization ; Polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; RAFT/MADIX macromolecular design by interchange of xanthates (RAFT/MADIX) ; Rafts ; reversible addition-fragmentation chain transfer polymerization (RAFT) ; Vinyl acetate ; xanthate</subject><ispartof>Journal of polymer science. Part A, Polymer chemistry, 2012-05, Vol.50 (10), p.1997-2007</ispartof><rights>Copyright © 2012 Wiley Periodicals, Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4454-49292320845893e9d6c0e4893a7b59e8095b96292a8ca2bb8dafa16275370cef3</citedby><cites>FETCH-LOGICAL-c4454-49292320845893e9d6c0e4893a7b59e8095b96292a8ca2bb8dafa16275370cef3</cites><orcidid>0000-0002-9889-3470 ; 0000-0002-9718-2239</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpola.25974$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpola.25974$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25784612$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00686413$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Dufils, P-E.</creatorcontrib><creatorcontrib>David, G.</creatorcontrib><creatorcontrib>Boutevin, B.</creatorcontrib><creatorcontrib>Woodward, G.</creatorcontrib><creatorcontrib>Otter, G.</creatorcontrib><creatorcontrib>Guinaudeau, A.</creatorcontrib><creatorcontrib>Mazières, S.</creatorcontrib><creatorcontrib>Destarac, M.</creatorcontrib><title>Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization</title><title>Journal of polymer science. Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>Four different xanthates containing either phosphonate or bisphosphonate moieties were synthesized with high degree of purity. These xanthates were used as chain transfer agents (CTA) in the RAFT/MADIX polymerization of vinyl acetate (VAc) to prepare end‐capped poly(VAc). The rate of VAc polymerization in the presence of these new CTAs was shown to be similar to that obtained with conventional xanthate, that is, (methyl ethoxycarbonothioyl) sulfanyl acetate. Good control of VAc polymerization was also obtained since the molecular weight increased linearly with monomer conversion for each phosphonate‐containing xanthate. Low‐PDI values were obtained, ascribed to efficient exchange during RAFT/MADIX polymerization. Cex value was therefore calculated to about 25, based on RAFT/MADIX of VAc in the presence of rhodixan A1/VAc adduct. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
A new series of phosphonate/bisphosphonate‐containing xanthates was efficiently synthesized and used as chain transfer agents in the RAFT/MADIX polymerization of VAc. Very good control of the VAc polymerization was obtained for each xanthate, thus leading to PVAc end‐capped with either phosphonate or bisphosphonate moieties.</description><subject>Acetates</subject><subject>Applied sciences</subject><subject>bisphosphonate</subject><subject>Chain transfer</subject><subject>Chemical Sciences</subject><subject>Conversion</subject><subject>Exact sciences and technology</subject><subject>heteroatom-containing polymers</subject><subject>kinetics</subject><subject>Mathematical analysis</subject><subject>Monomers</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(vinyl acetate)</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>RAFT/MADIX macromolecular design by interchange of xanthates (RAFT/MADIX)</subject><subject>Rafts</subject><subject>reversible addition-fragmentation chain transfer polymerization (RAFT)</subject><subject>Vinyl acetate</subject><subject>xanthate</subject><issn>0887-624X</issn><issn>0449-296X</issn><issn>1099-0518</issn><issn>1542-9350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kEtv00AURkeISoTChl-QDVKL5Hbej6WV0rQifYi20N3oejJWBhw7zLgF99czqUuWrO7Vvec7iw-hDwQfEYzp8aZr4IgKo_grNCHYmAILol-jCdZaFZLy-zfobUo_MM4_oSfo5nrVpc2qa6H3Re_jOmy35TSLhoPH0A7NFJzv8-1wmoa2X_kUnvK_GqZfy9Pb44vy5Pz-mV77GJ6gD137Du3V0CT__mXuo7vTz7ezs2JxNT-flYvCcS54wQ01lFGsudCGebOUDnueV1CVMF5jIyojMwPaAa0qvYQaiKRKMIWdr9k-Ohy9K2jsJoY1xMF2EOxZubDbG8ZSS07YI8nswchuYvfrwaferkNyvmmg9d1DsgQzzbBgQmX004i62KUUfb1zE2y3Ldtty_a55Qx_fPFCctDUEVoX0i5BhdJcEpo5MnK_Q-OH_xjt9dWi_OcuxkxIvf-zy0D8aaViStjvl3M7I3J-Sb7N7Rf2Fy-rmh0</recordid><startdate>20120515</startdate><enddate>20120515</enddate><creator>Dufils, P-E.</creator><creator>David, G.</creator><creator>Boutevin, B.</creator><creator>Woodward, G.</creator><creator>Otter, G.</creator><creator>Guinaudeau, A.</creator><creator>Mazières, S.</creator><creator>Destarac, M.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>John Wiley & Sons</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-9889-3470</orcidid><orcidid>https://orcid.org/0000-0002-9718-2239</orcidid></search><sort><creationdate>20120515</creationdate><title>Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization</title><author>Dufils, P-E. ; David, G. ; Boutevin, B. ; Woodward, G. ; Otter, G. ; Guinaudeau, A. ; Mazières, S. ; Destarac, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4454-49292320845893e9d6c0e4893a7b59e8095b96292a8ca2bb8dafa16275370cef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Acetates</topic><topic>Applied sciences</topic><topic>bisphosphonate</topic><topic>Chain transfer</topic><topic>Chemical Sciences</topic><topic>Conversion</topic><topic>Exact sciences and technology</topic><topic>heteroatom-containing polymers</topic><topic>kinetics</topic><topic>Mathematical analysis</topic><topic>Monomers</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(vinyl acetate)</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>RAFT/MADIX macromolecular design by interchange of xanthates (RAFT/MADIX)</topic><topic>Rafts</topic><topic>reversible addition-fragmentation chain transfer polymerization (RAFT)</topic><topic>Vinyl acetate</topic><topic>xanthate</topic><toplevel>online_resources</toplevel><creatorcontrib>Dufils, P-E.</creatorcontrib><creatorcontrib>David, G.</creatorcontrib><creatorcontrib>Boutevin, B.</creatorcontrib><creatorcontrib>Woodward, G.</creatorcontrib><creatorcontrib>Otter, G.</creatorcontrib><creatorcontrib>Guinaudeau, A.</creatorcontrib><creatorcontrib>Mazières, S.</creatorcontrib><creatorcontrib>Destarac, M.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dufils, P-E.</au><au>David, G.</au><au>Boutevin, B.</au><au>Woodward, G.</au><au>Otter, G.</au><au>Guinaudeau, A.</au><au>Mazières, S.</au><au>Destarac, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>2012-05-15</date><risdate>2012</risdate><volume>50</volume><issue>10</issue><spage>1997</spage><epage>2007</epage><pages>1997-2007</pages><issn>0887-624X</issn><issn>0449-296X</issn><eissn>1099-0518</eissn><eissn>1542-9350</eissn><coden>JPLCAT</coden><abstract>Four different xanthates containing either phosphonate or bisphosphonate moieties were synthesized with high degree of purity. These xanthates were used as chain transfer agents (CTA) in the RAFT/MADIX polymerization of vinyl acetate (VAc) to prepare end‐capped poly(VAc). The rate of VAc polymerization in the presence of these new CTAs was shown to be similar to that obtained with conventional xanthate, that is, (methyl ethoxycarbonothioyl) sulfanyl acetate. Good control of VAc polymerization was also obtained since the molecular weight increased linearly with monomer conversion for each phosphonate‐containing xanthate. Low‐PDI values were obtained, ascribed to efficient exchange during RAFT/MADIX polymerization. Cex value was therefore calculated to about 25, based on RAFT/MADIX of VAc in the presence of rhodixan A1/VAc adduct. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
A new series of phosphonate/bisphosphonate‐containing xanthates was efficiently synthesized and used as chain transfer agents in the RAFT/MADIX polymerization of VAc. Very good control of the VAc polymerization was obtained for each xanthate, thus leading to PVAc end‐capped with either phosphonate or bisphosphonate moieties.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/pola.25974</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-9889-3470</orcidid><orcidid>https://orcid.org/0000-0002-9718-2239</orcidid></addata></record> |
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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 2012-05, Vol.50 (10), p.1997-2007 |
| issn | 0887-624X 0449-296X 1099-0518 1542-9350 |
| language | eng |
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| subjects | Acetates Applied sciences bisphosphonate Chain transfer Chemical Sciences Conversion Exact sciences and technology heteroatom-containing polymers kinetics Mathematical analysis Monomers Organic polymers Physicochemistry of polymers poly(vinyl acetate) Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts RAFT/MADIX macromolecular design by interchange of xanthates (RAFT/MADIX) Rafts reversible addition-fragmentation chain transfer polymerization (RAFT) Vinyl acetate xanthate |
| title | Phosphonate-terminated poly(vinyl acetate) synthesized by RAFT/MADIX polymerization |
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