Successive dynamical steps of photoinduced switching of a molecular Fe(III) spin-crossover material by time-resolved x-ray diffraction

We investigate the out-of-equilibrium switching dynamics of a molecular Fe(III) spin-crossover solid triggered by a femtosecond laser flash. The time-resolved x-ray diffraction and optical results show that the dynamics span from subpicosecond local photoswitching followed by volume expansion (nanos...

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Veröffentlicht in:Physical review letters 2009-07, Vol.103 (2), p.028301-028301, Article 028301
Hauptverfasser: Lorenc, M, Hébert, J, Moisan, N, Trzop, E, Servol, M, Buron-Le Cointe, M, Cailleau, H, Boillot, M L, Pontecorvo, E, Wulff, M, Koshihara, S, Collet, E
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Sprache:eng
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