Phase Equilibrium Modeling of Structure H Clathrate Hydrates of Methane + Water “Insoluble” Hydrocarbon Promoter Using Group Contribution-Support Vector Machine Technique
In this work, the group contribution (GC) method is coupled with the least-squares support vector machine (LSSVM) mathematical algorithm to develop a model for representation/prediction of the dissociation conditions of structure H (sH) clathrate hydrates of methane with 21 hydrocarbon promoters nam...
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Veröffentlicht in: | Industrial & engineering chemistry research 2011-11, Vol.50 (22), p.12807-12814 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this work, the group contribution (GC) method is coupled with the least-squares support vector machine (LSSVM) mathematical algorithm to develop a model for representation/prediction of the dissociation conditions of structure H (sH) clathrate hydrates of methane with 21 hydrocarbon promoters namely as water “insoluble” promoters. Almost all of available literature data are studied to present a reliable model validated by the following statistical parameters: absolute average relative deviations (AARD) of the represented/predicted dissociation pressures from the reported experimental values: about 1.6%, and squared correlation coefficient: 0.99. |
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ISSN: | 0888-5885 1520-5045 |
DOI: | 10.1021/ie2011164 |