Phase Equilibrium Modeling of Structure H Clathrate Hydrates of Methane + Water “Insoluble” Hydrocarbon Promoter Using Group Contribution-Support Vector Machine Technique

In this work, the group contribution (GC) method is coupled with the least-squares support vector machine (LSSVM) mathematical algorithm to develop a model for representation/prediction of the dissociation conditions of structure H (sH) clathrate hydrates of methane with 21 hydrocarbon promoters nam...

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Veröffentlicht in:Industrial & engineering chemistry research 2011-11, Vol.50 (22), p.12807-12814
Hauptverfasser: Eslamimanesh, Ali, Gharagheizi, Farhad, Mohammadi, Amir H, Richon, Dominique, Illbeigi, Mohammad, Fazlali, Alireza, Forghani, Amir Ahmad, Yazdizadeh, Mohammad
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Sprache:eng
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Zusammenfassung:In this work, the group contribution (GC) method is coupled with the least-squares support vector machine (LSSVM) mathematical algorithm to develop a model for representation/prediction of the dissociation conditions of structure H (sH) clathrate hydrates of methane with 21 hydrocarbon promoters namely as water “insoluble” promoters. Almost all of available literature data are studied to present a reliable model validated by the following statistical parameters: absolute average relative deviations (AARD) of the represented/predicted dissociation pressures from the reported experimental values: about 1.6%, and squared correlation coefficient: 0.99.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie2011164