Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48
Ordered mesoporous silica with hexagonal and cubic structure, type MCM-41 and MCM-48 respectively, were synthesized under basic media using pure silica, cetyltrimethylammonium bromide and tetramethylammonium hydroxide, for MCM-41 and tetraethylorthosilica, cetyltrimethylammonium and NaOH for MCM-48....
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| Veröffentlicht in: | Journal of hazardous materials 2009-11, Vol.171 (1), p.1001-1008 |
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| creator | Benhamou, A. Baudu, M. Derriche, Z. Basly, J.P. |
| description | Ordered mesoporous silica with hexagonal and cubic structure, type MCM-41 and MCM-48 respectively, were synthesized under basic media using pure silica, cetyltrimethylammonium bromide and tetramethylammonium hydroxide, for MCM-41 and tetraethylorthosilica, cetyltrimethylammonium and NaOH for MCM-48. The expanded materials were prepared by post-synthesis method with N-N dimethyldodecylamine (DMDDA) and dodecylamine (DDA). Small angle X-ray diffraction, nitrogen adsorption–desorption measurements, FT-IR and thermogravimetry were used to characterize the samples. The expanded materials were tested for adsorption of Cd
2+, Co
2+, Cu
2+ and Pb
2+ in aqueous solution. Aminated materials were found to be fast adsorbents for metallic ions cation with affinity for Cu
2+, Pb
2+, than for Cd
2+ and Co
2+ from single solution. In mixed metallic ions cation solutions, competition by the adsorption sites is likely to occur, the adsorption preference is for Cu
2+and Pb
2+. The kinetic of the reaction is very rapid and follow pseudo-second order and clearly indicated that Langmuir model describe better the for metal ions adsorption on aminated mesoporous material than Freundlich model. |
| doi_str_mv | 10.1016/j.jhazmat.2009.06.106 |
| format | Article |
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2+, Co
2+, Cu
2+ and Pb
2+ in aqueous solution. Aminated materials were found to be fast adsorbents for metallic ions cation with affinity for Cu
2+, Pb
2+, than for Cd
2+ and Co
2+ from single solution. In mixed metallic ions cation solutions, competition by the adsorption sites is likely to occur, the adsorption preference is for Cu
2+and Pb
2+. The kinetic of the reaction is very rapid and follow pseudo-second order and clearly indicated that Langmuir model describe better the for metal ions adsorption on aminated mesoporous material than Freundlich model.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2009.06.106</identifier><identifier>PMID: 19615819</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Adsorption ; Amine ; Amines - chemistry ; Analytical chemistry ; Applied sciences ; Cations ; Chemical engineering ; Chemical Sciences ; Copper - chemistry ; Diffraction ; Environmental Sciences ; Exact sciences and technology ; Expansion ; Hydroxides ; Ions ; Kinetics ; Lead - chemistry ; Material chemistry ; Mathematical models ; Mesoporous materials ; Metal ions ; Metals, Heavy - chemistry ; Metals, Heavy - isolation & purification ; Nitrogen - chemistry ; Pollution ; Silicon dioxide ; Silicon Dioxide - chemistry ; Spectroscopy, Fourier Transform Infrared ; Water Pollutants, Chemical - chemistry ; Water Pollutants, Chemical - isolation & purification ; Water Purification - methods ; X-Ray Diffraction</subject><ispartof>Journal of hazardous materials, 2009-11, Vol.171 (1), p.1001-1008</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c531t-bc16f8fc379949659f2c6059f25d6f18b34df3174c5d069139c2d93d088571713</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jhazmat.2009.06.106$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22586636$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19615819$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://unilim.hal.science/hal-00653594$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Benhamou, A.</creatorcontrib><creatorcontrib>Baudu, M.</creatorcontrib><creatorcontrib>Derriche, Z.</creatorcontrib><creatorcontrib>Basly, J.P.</creatorcontrib><title>Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>Ordered mesoporous silica with hexagonal and cubic structure, type MCM-41 and MCM-48 respectively, were synthesized under basic media using pure silica, cetyltrimethylammonium bromide and tetramethylammonium hydroxide, for MCM-41 and tetraethylorthosilica, cetyltrimethylammonium and NaOH for MCM-48. The expanded materials were prepared by post-synthesis method with N-N dimethyldodecylamine (DMDDA) and dodecylamine (DDA). Small angle X-ray diffraction, nitrogen adsorption–desorption measurements, FT-IR and thermogravimetry were used to characterize the samples. The expanded materials were tested for adsorption of Cd
2+, Co
2+, Cu
2+ and Pb
2+ in aqueous solution. Aminated materials were found to be fast adsorbents for metallic ions cation with affinity for Cu
2+, Pb
2+, than for Cd
2+ and Co
2+ from single solution. In mixed metallic ions cation solutions, competition by the adsorption sites is likely to occur, the adsorption preference is for Cu
2+and Pb
2+. The kinetic of the reaction is very rapid and follow pseudo-second order and clearly indicated that Langmuir model describe better the for metal ions adsorption on aminated mesoporous material than Freundlich model.</description><subject>Adsorption</subject><subject>Amine</subject><subject>Amines - chemistry</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Cations</subject><subject>Chemical engineering</subject><subject>Chemical Sciences</subject><subject>Copper - chemistry</subject><subject>Diffraction</subject><subject>Environmental Sciences</subject><subject>Exact sciences and technology</subject><subject>Expansion</subject><subject>Hydroxides</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Lead - chemistry</subject><subject>Material chemistry</subject><subject>Mathematical models</subject><subject>Mesoporous materials</subject><subject>Metal ions</subject><subject>Metals, Heavy - chemistry</subject><subject>Metals, Heavy - isolation & purification</subject><subject>Nitrogen - chemistry</subject><subject>Pollution</subject><subject>Silicon dioxide</subject><subject>Silicon Dioxide - chemistry</subject><subject>Spectroscopy, Fourier Transform Infrared</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollutants, Chemical - isolation & purification</subject><subject>Water Purification - methods</subject><subject>X-Ray Diffraction</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkctuEzEUhi0EoqHwCKDZgMRiwjnjy9grFEVAkVKxANaW44viaC7FnkRqnx6PMmqXXR2dX9-5_oS8R1gjoPhyXB8P5qE307oBUGsQRRYvyAplS2tKqXhJVkCB1VQqdkXe5HwEAGw5e02uUAnkEtWK7Db_Tn485ergzfm-6v1kulwl349n01XjUJk-Dr4Op8FOcRxMFx-8q37H-nZ7WzOszPCUybfkVSjl_t0Sr8nf79_-bG_q3a8fP7ebXW05xaneWxRBBktbpZgSXIXGCpgDdyKg3FPmAsWWWe5AKKTKNk5RB1LyFluk1-Tzpe_BdPouxd6kez2aqG82Oz1rAIJTrth5Zj9d2Ls0llPzpPuYre86M8x3a8rKACHFs2AD5WGylQXkF9CmMefkw-MKCHr2Rh_14o2evdEgijwP-LAMOO17756qFjMK8HEBTLamC8kMNuZHrmm4FILOjb5eOF9-fI4-6WyjH6x3MXk7aTfGZ1b5DzViq04</recordid><startdate>20091115</startdate><enddate>20091115</enddate><creator>Benhamou, A.</creator><creator>Baudu, M.</creator><creator>Derriche, Z.</creator><creator>Basly, J.P.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>7U7</scope><scope>C1K</scope><scope>SOI</scope><scope>7SU</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>1XC</scope></search><sort><creationdate>20091115</creationdate><title>Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48</title><author>Benhamou, A. ; Baudu, M. ; Derriche, Z. ; Basly, J.P.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c531t-bc16f8fc379949659f2c6059f25d6f18b34df3174c5d069139c2d93d088571713</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Adsorption</topic><topic>Amine</topic><topic>Amines - chemistry</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Cations</topic><topic>Chemical engineering</topic><topic>Chemical Sciences</topic><topic>Copper - chemistry</topic><topic>Diffraction</topic><topic>Environmental Sciences</topic><topic>Exact sciences and technology</topic><topic>Expansion</topic><topic>Hydroxides</topic><topic>Ions</topic><topic>Kinetics</topic><topic>Lead - chemistry</topic><topic>Material chemistry</topic><topic>Mathematical models</topic><topic>Mesoporous materials</topic><topic>Metal ions</topic><topic>Metals, Heavy - chemistry</topic><topic>Metals, Heavy - isolation & purification</topic><topic>Nitrogen - chemistry</topic><topic>Pollution</topic><topic>Silicon dioxide</topic><topic>Silicon Dioxide - chemistry</topic><topic>Spectroscopy, Fourier Transform Infrared</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Pollutants, Chemical - isolation & purification</topic><topic>Water Purification - methods</topic><topic>X-Ray Diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Benhamou, A.</creatorcontrib><creatorcontrib>Baudu, M.</creatorcontrib><creatorcontrib>Derriche, Z.</creatorcontrib><creatorcontrib>Basly, J.P.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Benhamou, A.</au><au>Baudu, M.</au><au>Derriche, Z.</au><au>Basly, J.P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2009-11-15</date><risdate>2009</risdate><volume>171</volume><issue>1</issue><spage>1001</spage><epage>1008</epage><pages>1001-1008</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>Ordered mesoporous silica with hexagonal and cubic structure, type MCM-41 and MCM-48 respectively, were synthesized under basic media using pure silica, cetyltrimethylammonium bromide and tetramethylammonium hydroxide, for MCM-41 and tetraethylorthosilica, cetyltrimethylammonium and NaOH for MCM-48. The expanded materials were prepared by post-synthesis method with N-N dimethyldodecylamine (DMDDA) and dodecylamine (DDA). Small angle X-ray diffraction, nitrogen adsorption–desorption measurements, FT-IR and thermogravimetry were used to characterize the samples. The expanded materials were tested for adsorption of Cd
2+, Co
2+, Cu
2+ and Pb
2+ in aqueous solution. Aminated materials were found to be fast adsorbents for metallic ions cation with affinity for Cu
2+, Pb
2+, than for Cd
2+ and Co
2+ from single solution. In mixed metallic ions cation solutions, competition by the adsorption sites is likely to occur, the adsorption preference is for Cu
2+and Pb
2+. The kinetic of the reaction is very rapid and follow pseudo-second order and clearly indicated that Langmuir model describe better the for metal ions adsorption on aminated mesoporous material than Freundlich model.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>19615819</pmid><doi>10.1016/j.jhazmat.2009.06.106</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of hazardous materials, 2009-11, Vol.171 (1), p.1001-1008 |
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| source | MEDLINE; Elsevier ScienceDirect Journals Complete |
| subjects | Adsorption Amine Amines - chemistry Analytical chemistry Applied sciences Cations Chemical engineering Chemical Sciences Copper - chemistry Diffraction Environmental Sciences Exact sciences and technology Expansion Hydroxides Ions Kinetics Lead - chemistry Material chemistry Mathematical models Mesoporous materials Metal ions Metals, Heavy - chemistry Metals, Heavy - isolation & purification Nitrogen - chemistry Pollution Silicon dioxide Silicon Dioxide - chemistry Spectroscopy, Fourier Transform Infrared Water Pollutants, Chemical - chemistry Water Pollutants, Chemical - isolation & purification Water Purification - methods X-Ray Diffraction |
| title | Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48 |
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