Stability of surfactant-free high internal phase emulsions and its tailoring morphology of porous polymers based on the emulsions
Stable water-in-oil (w/o) high internal phase emulsions (HIPEs) having an internal phase of up to 95 vol% were prepared. The poly(styrene-methyl methacrylate-acrylic acid) (P(St-MMA-AA)) copolymer particles were used as stabilizer. The HIPEs prepared with addition of copolymer particles to the aqueo...
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| Veröffentlicht in: | Polymer (Guilford) 2011-09, Vol.52 (21), p.4881-4890 |
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| creator | Zhang, Shengmiao Zhu, Yun Hua, Ye Jegat, Corinne Chen, Jianding Taha, Mohamed |
| description | Stable water-in-oil (w/o) high internal phase emulsions (HIPEs) having an internal phase of up to 95 vol% were prepared. The poly(styrene-methyl methacrylate-acrylic acid) (P(St-MMA-AA)) copolymer particles were used as stabilizer. The HIPEs prepared with addition of copolymer particles to the aqueous phase were stabilized by copolymer particles initially, followed by the mixture of copolymer particles and copolymer as the particles eventually dissolves in the organic phase, and finally by only copolymer. Stable w/o HIPEs having an internal phase of up to 92 vol% were also formed with P(St-MMA-AA) copolymer dissolved in the organic phase as the sole stabilizer. Porous polymers (polyHIPEs) were prepared based on these two types of surfactant-free HIPEs. The morphology of the polyHIPEs, such as the surface roughness of the voids and average void diameter, were tailored by tuning the internal phase volume fraction, NaCl, copolymer, and crosslinker concentrations.
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| doi_str_mv | 10.1016/j.polymer.2011.08.022 |
| format | Article |
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[Display omitted]</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/j.polymer.2011.08.022</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Chemical Sciences ; Copolymer particle ; Copolymerization ; Copolymers ; Dissolution ; Emulsions ; Exact sciences and technology ; High internal phase emulsion ; Material chemistry ; Morphology ; Organic polymers ; Physicochemistry of polymers ; Polymers ; Polystyrene resins ; Porous polymer ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; surface roughness ; Tuning ; Voids</subject><ispartof>Polymer (Guilford), 2011-09, Vol.52 (21), p.4881-4890</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c466t-5e4328cabca00a1d01b7e8991402d050d59b08fc83d8dbf9f61ad25ecda7d7fd3</citedby><cites>FETCH-LOGICAL-c466t-5e4328cabca00a1d01b7e8991402d050d59b08fc83d8dbf9f61ad25ecda7d7fd3</cites><orcidid>0000-0002-7568-2013</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0032386111006884$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65534</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24698671$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00648096$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Shengmiao</creatorcontrib><creatorcontrib>Zhu, Yun</creatorcontrib><creatorcontrib>Hua, Ye</creatorcontrib><creatorcontrib>Jegat, Corinne</creatorcontrib><creatorcontrib>Chen, Jianding</creatorcontrib><creatorcontrib>Taha, Mohamed</creatorcontrib><title>Stability of surfactant-free high internal phase emulsions and its tailoring morphology of porous polymers based on the emulsions</title><title>Polymer (Guilford)</title><description>Stable water-in-oil (w/o) high internal phase emulsions (HIPEs) having an internal phase of up to 95 vol% were prepared. The poly(styrene-methyl methacrylate-acrylic acid) (P(St-MMA-AA)) copolymer particles were used as stabilizer. The HIPEs prepared with addition of copolymer particles to the aqueous phase were stabilized by copolymer particles initially, followed by the mixture of copolymer particles and copolymer as the particles eventually dissolves in the organic phase, and finally by only copolymer. Stable w/o HIPEs having an internal phase of up to 92 vol% were also formed with P(St-MMA-AA) copolymer dissolved in the organic phase as the sole stabilizer. Porous polymers (polyHIPEs) were prepared based on these two types of surfactant-free HIPEs. The morphology of the polyHIPEs, such as the surface roughness of the voids and average void diameter, were tailored by tuning the internal phase volume fraction, NaCl, copolymer, and crosslinker concentrations.
[Display omitted]</description><subject>Applied sciences</subject><subject>Chemical Sciences</subject><subject>Copolymer particle</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Dissolution</subject><subject>Emulsions</subject><subject>Exact sciences and technology</subject><subject>High internal phase emulsion</subject><subject>Material chemistry</subject><subject>Morphology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Polystyrene resins</subject><subject>Porous polymer</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>surface roughness</subject><subject>Tuning</subject><subject>Voids</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkUuLFDEUhQtRsB39CWI2Ii6qvUk9OlnJMKgjNMxinHW4lUdXmlSlTNIDvfSfT9puBneuAuE75557T1W9p7CmQPsv-_US_HEycc2A0jXwNTD2olpRvmlqxgR9Wa0AGlY3vKevqzcp7QGAdaxdVX_uMw7Ou3wkwZJ0iBZVxjnXNhpDRrcbiZuziTN6soyYDDHTwScX5kRw1sTlRDI6H6Kbd2QKcRmDD7u_bkuI4ZDIJVwiQ5FrEmaSx39s3lavLPpk3l3eq-rh-7dfN7f19u7Hz5vrba3avs91Z9qGcYWDQgCkGuiwMVwI2gLT0IHuxADcKt5orgcrbE9Rs84ojRu9sbq5qj6ffUf0coluwniUAZ28vd7K0x9A33IQ_SMt7Kczu8Tw-2BSlpNLyniPsykrScH6hpY4J7I7kyqGlKKxz9YU5KkduZeXA8hTOxK4LO0U3cfLBEwKvY04K5eexaztBe83J_8PZ85ikLiLhXm4L0ZdaVCIphWF-HomTDneoytzknJmVka7aFSWOrj_ZHkCBVC0uA</recordid><startdate>20110929</startdate><enddate>20110929</enddate><creator>Zhang, Shengmiao</creator><creator>Zhu, Yun</creator><creator>Hua, Ye</creator><creator>Jegat, Corinne</creator><creator>Chen, Jianding</creator><creator>Taha, Mohamed</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-7568-2013</orcidid></search><sort><creationdate>20110929</creationdate><title>Stability of surfactant-free high internal phase emulsions and its tailoring morphology of porous polymers based on the emulsions</title><author>Zhang, Shengmiao ; Zhu, Yun ; Hua, Ye ; Jegat, Corinne ; Chen, Jianding ; Taha, Mohamed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c466t-5e4328cabca00a1d01b7e8991402d050d59b08fc83d8dbf9f61ad25ecda7d7fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Chemical Sciences</topic><topic>Copolymer particle</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Dissolution</topic><topic>Emulsions</topic><topic>Exact sciences and technology</topic><topic>High internal phase emulsion</topic><topic>Material chemistry</topic><topic>Morphology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Polystyrene resins</topic><topic>Porous polymer</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>surface roughness</topic><topic>Tuning</topic><topic>Voids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Shengmiao</creatorcontrib><creatorcontrib>Zhu, Yun</creatorcontrib><creatorcontrib>Hua, Ye</creatorcontrib><creatorcontrib>Jegat, Corinne</creatorcontrib><creatorcontrib>Chen, Jianding</creatorcontrib><creatorcontrib>Taha, Mohamed</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Shengmiao</au><au>Zhu, Yun</au><au>Hua, Ye</au><au>Jegat, Corinne</au><au>Chen, Jianding</au><au>Taha, Mohamed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stability of surfactant-free high internal phase emulsions and its tailoring morphology of porous polymers based on the emulsions</atitle><jtitle>Polymer (Guilford)</jtitle><date>2011-09-29</date><risdate>2011</risdate><volume>52</volume><issue>21</issue><spage>4881</spage><epage>4890</epage><pages>4881-4890</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>Stable water-in-oil (w/o) high internal phase emulsions (HIPEs) having an internal phase of up to 95 vol% were prepared. The poly(styrene-methyl methacrylate-acrylic acid) (P(St-MMA-AA)) copolymer particles were used as stabilizer. The HIPEs prepared with addition of copolymer particles to the aqueous phase were stabilized by copolymer particles initially, followed by the mixture of copolymer particles and copolymer as the particles eventually dissolves in the organic phase, and finally by only copolymer. Stable w/o HIPEs having an internal phase of up to 92 vol% were also formed with P(St-MMA-AA) copolymer dissolved in the organic phase as the sole stabilizer. Porous polymers (polyHIPEs) were prepared based on these two types of surfactant-free HIPEs. The morphology of the polyHIPEs, such as the surface roughness of the voids and average void diameter, were tailored by tuning the internal phase volume fraction, NaCl, copolymer, and crosslinker concentrations.
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Chemical Sciences Copolymer particle Copolymerization Copolymers Dissolution Emulsions Exact sciences and technology High internal phase emulsion Material chemistry Morphology Organic polymers Physicochemistry of polymers Polymers Polystyrene resins Porous polymer Preparation, kinetics, thermodynamics, mechanism and catalysts surface roughness Tuning Voids |
| title | Stability of surfactant-free high internal phase emulsions and its tailoring morphology of porous polymers based on the emulsions |
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