Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite
[Display omitted] ► Micro/mesoporous catalysts were prepared by recrystallization of ferrierite. ► The degree of recrystallization was controlled by alkali concentration. ► A significant increase of acid sites accessibility was observed. ► New materials showed improved catalytic activity in n-butene...
Gespeichert in:
| Veröffentlicht in: | Microporous and mesoporous materials 2011-12, Vol.146 (1), p.201-207 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 207 |
|---|---|
| container_issue | 1 |
| container_start_page | 201 |
| container_title | Microporous and mesoporous materials |
| container_volume | 146 |
| creator | Khitev, Yu.P. Kolyagin, Yu.G. Ivanova, I.I. Ponomareva, O.A. Thibault-Starzyk, F. Gilson, J.-P. Fernandez, C. Fajula, F. |
| description | [Display omitted]
► Micro/mesoporous catalysts were prepared by recrystallization of ferrierite. ► The degree of recrystallization was controlled by alkali concentration. ► A significant increase of acid sites accessibility was observed. ► New materials showed improved catalytic activity in n-butene isomerization.
Hierarchical zeolitic catalysts with varying ratios of micro- and mesoporosity were prepared by recrystallization of ferrierite (FER) in alkaline solution in the presence of cetyltrimethylammonium bromide. The catalysts were characterized by XRD, TPD-NH
3, FT-IR, nitrogen adsorption–desorption, SEM, TEM. The influence of alkali concentration on the distribution of micro- and mesopores is discussed. The recrystallization process led to a significant increase of accessibility of the acid sites, together with a decrease of the total acidity. The catalytic properties were investigated in 1-butene isomerization. All recrystallized materials showed improved catalytic activity and selectivity in isomerization. |
| doi_str_mv | 10.1016/j.micromeso.2011.05.003 |
| format | Article |
| fullrecord | <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_00645124v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S138718111100223X</els_id><sourcerecordid>oai_HAL_hal_00645124v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c415t-e58247e5abf15e11323adb5a491d5a920debd68cc4e84a7d3b859455812c47673</originalsourceid><addsrcrecordid>eNqFUMlqwzAQNaWFpmm_obr2YEdjSV6OISRNIVDochayNMYKthUkN5B-fe2m5NrTDDNv4b0oegSaAIVssU86q73rMLgkpQAJFQml7CqaQZGzmNGSXY87K_IYCoDb6C6EPaWQQwqzqHo_9UODwQaiekO0GlR7GqwmB-8O6AeLgbiaNBa98rqxWrXk128xGR6cd1-BdGpAb1UbSKUCGuJ6slm_kW90rR3wPrqpxx8-_M159LlZf6y28e71-WW13MWagxhiFEXKcxSqqkEgAEuZMpVQvAQjVJlSg5XJCq05FlzlhlWFKLkQBaSa51nO5tHTWbdRrTx42yl_kk5ZuV3u5HSjNOMCUn6EEZufsWOSEDzWFwJQOdUq9_JSq5xqlVSMAmxkLs9MHKMcx1pk0BZ7jcZ61IM0zv6r8QN6joaA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Khitev, Yu.P. ; Kolyagin, Yu.G. ; Ivanova, I.I. ; Ponomareva, O.A. ; Thibault-Starzyk, F. ; Gilson, J.-P. ; Fernandez, C. ; Fajula, F.</creator><creatorcontrib>Khitev, Yu.P. ; Kolyagin, Yu.G. ; Ivanova, I.I. ; Ponomareva, O.A. ; Thibault-Starzyk, F. ; Gilson, J.-P. ; Fernandez, C. ; Fajula, F.</creatorcontrib><description>[Display omitted]
► Micro/mesoporous catalysts were prepared by recrystallization of ferrierite. ► The degree of recrystallization was controlled by alkali concentration. ► A significant increase of acid sites accessibility was observed. ► New materials showed improved catalytic activity in n-butene isomerization.
Hierarchical zeolitic catalysts with varying ratios of micro- and mesoporosity were prepared by recrystallization of ferrierite (FER) in alkaline solution in the presence of cetyltrimethylammonium bromide. The catalysts were characterized by XRD, TPD-NH
3, FT-IR, nitrogen adsorption–desorption, SEM, TEM. The influence of alkali concentration on the distribution of micro- and mesopores is discussed. The recrystallization process led to a significant increase of accessibility of the acid sites, together with a decrease of the total acidity. The catalytic properties were investigated in 1-butene isomerization. All recrystallized materials showed improved catalytic activity and selectivity in isomerization.</description><identifier>ISSN: 1387-1811</identifier><identifier>EISSN: 1873-3093</identifier><identifier>DOI: 10.1016/j.micromeso.2011.05.003</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Chemical Sciences ; Ferrierite ; Material chemistry ; Micro/mesoporous catalysts ; Zeolites</subject><ispartof>Microporous and mesoporous materials, 2011-12, Vol.146 (1), p.201-207</ispartof><rights>2011 Elsevier Inc.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c415t-e58247e5abf15e11323adb5a491d5a920debd68cc4e84a7d3b859455812c47673</citedby><cites>FETCH-LOGICAL-c415t-e58247e5abf15e11323adb5a491d5a920debd68cc4e84a7d3b859455812c47673</cites><orcidid>0000-0002-5476-3148 ; 0000-0002-8095-0860 ; 0000-0002-3543-8163</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.micromeso.2011.05.003$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00645124$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Khitev, Yu.P.</creatorcontrib><creatorcontrib>Kolyagin, Yu.G.</creatorcontrib><creatorcontrib>Ivanova, I.I.</creatorcontrib><creatorcontrib>Ponomareva, O.A.</creatorcontrib><creatorcontrib>Thibault-Starzyk, F.</creatorcontrib><creatorcontrib>Gilson, J.-P.</creatorcontrib><creatorcontrib>Fernandez, C.</creatorcontrib><creatorcontrib>Fajula, F.</creatorcontrib><title>Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite</title><title>Microporous and mesoporous materials</title><description>[Display omitted]
► Micro/mesoporous catalysts were prepared by recrystallization of ferrierite. ► The degree of recrystallization was controlled by alkali concentration. ► A significant increase of acid sites accessibility was observed. ► New materials showed improved catalytic activity in n-butene isomerization.
Hierarchical zeolitic catalysts with varying ratios of micro- and mesoporosity were prepared by recrystallization of ferrierite (FER) in alkaline solution in the presence of cetyltrimethylammonium bromide. The catalysts were characterized by XRD, TPD-NH
3, FT-IR, nitrogen adsorption–desorption, SEM, TEM. The influence of alkali concentration on the distribution of micro- and mesopores is discussed. The recrystallization process led to a significant increase of accessibility of the acid sites, together with a decrease of the total acidity. The catalytic properties were investigated in 1-butene isomerization. All recrystallized materials showed improved catalytic activity and selectivity in isomerization.</description><subject>Chemical Sciences</subject><subject>Ferrierite</subject><subject>Material chemistry</subject><subject>Micro/mesoporous catalysts</subject><subject>Zeolites</subject><issn>1387-1811</issn><issn>1873-3093</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFUMlqwzAQNaWFpmm_obr2YEdjSV6OISRNIVDochayNMYKthUkN5B-fe2m5NrTDDNv4b0oegSaAIVssU86q73rMLgkpQAJFQml7CqaQZGzmNGSXY87K_IYCoDb6C6EPaWQQwqzqHo_9UODwQaiekO0GlR7GqwmB-8O6AeLgbiaNBa98rqxWrXk128xGR6cd1-BdGpAb1UbSKUCGuJ6slm_kW90rR3wPrqpxx8-_M159LlZf6y28e71-WW13MWagxhiFEXKcxSqqkEgAEuZMpVQvAQjVJlSg5XJCq05FlzlhlWFKLkQBaSa51nO5tHTWbdRrTx42yl_kk5ZuV3u5HSjNOMCUn6EEZufsWOSEDzWFwJQOdUq9_JSq5xqlVSMAmxkLs9MHKMcx1pk0BZ7jcZ61IM0zv6r8QN6joaA</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Khitev, Yu.P.</creator><creator>Kolyagin, Yu.G.</creator><creator>Ivanova, I.I.</creator><creator>Ponomareva, O.A.</creator><creator>Thibault-Starzyk, F.</creator><creator>Gilson, J.-P.</creator><creator>Fernandez, C.</creator><creator>Fajula, F.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5476-3148</orcidid><orcidid>https://orcid.org/0000-0002-8095-0860</orcidid><orcidid>https://orcid.org/0000-0002-3543-8163</orcidid></search><sort><creationdate>20111201</creationdate><title>Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite</title><author>Khitev, Yu.P. ; Kolyagin, Yu.G. ; Ivanova, I.I. ; Ponomareva, O.A. ; Thibault-Starzyk, F. ; Gilson, J.-P. ; Fernandez, C. ; Fajula, F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c415t-e58247e5abf15e11323adb5a491d5a920debd68cc4e84a7d3b859455812c47673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Chemical Sciences</topic><topic>Ferrierite</topic><topic>Material chemistry</topic><topic>Micro/mesoporous catalysts</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khitev, Yu.P.</creatorcontrib><creatorcontrib>Kolyagin, Yu.G.</creatorcontrib><creatorcontrib>Ivanova, I.I.</creatorcontrib><creatorcontrib>Ponomareva, O.A.</creatorcontrib><creatorcontrib>Thibault-Starzyk, F.</creatorcontrib><creatorcontrib>Gilson, J.-P.</creatorcontrib><creatorcontrib>Fernandez, C.</creatorcontrib><creatorcontrib>Fajula, F.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Microporous and mesoporous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khitev, Yu.P.</au><au>Kolyagin, Yu.G.</au><au>Ivanova, I.I.</au><au>Ponomareva, O.A.</au><au>Thibault-Starzyk, F.</au><au>Gilson, J.-P.</au><au>Fernandez, C.</au><au>Fajula, F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite</atitle><jtitle>Microporous and mesoporous materials</jtitle><date>2011-12-01</date><risdate>2011</risdate><volume>146</volume><issue>1</issue><spage>201</spage><epage>207</epage><pages>201-207</pages><issn>1387-1811</issn><eissn>1873-3093</eissn><abstract>[Display omitted]
► Micro/mesoporous catalysts were prepared by recrystallization of ferrierite. ► The degree of recrystallization was controlled by alkali concentration. ► A significant increase of acid sites accessibility was observed. ► New materials showed improved catalytic activity in n-butene isomerization.
Hierarchical zeolitic catalysts with varying ratios of micro- and mesoporosity were prepared by recrystallization of ferrierite (FER) in alkaline solution in the presence of cetyltrimethylammonium bromide. The catalysts were characterized by XRD, TPD-NH
3, FT-IR, nitrogen adsorption–desorption, SEM, TEM. The influence of alkali concentration on the distribution of micro- and mesopores is discussed. The recrystallization process led to a significant increase of accessibility of the acid sites, together with a decrease of the total acidity. The catalytic properties were investigated in 1-butene isomerization. All recrystallized materials showed improved catalytic activity and selectivity in isomerization.</abstract><pub>Elsevier Inc</pub><doi>10.1016/j.micromeso.2011.05.003</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5476-3148</orcidid><orcidid>https://orcid.org/0000-0002-8095-0860</orcidid><orcidid>https://orcid.org/0000-0002-3543-8163</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1387-1811 |
| ispartof | Microporous and mesoporous materials, 2011-12, Vol.146 (1), p.201-207 |
| issn | 1387-1811 1873-3093 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00645124v1 |
| source | Elsevier ScienceDirect Journals Complete |
| subjects | Chemical Sciences Ferrierite Material chemistry Micro/mesoporous catalysts Zeolites |
| title | Synthesis and catalytic properties of hierarchical micro/mesoporous materials based on FER zeolite |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T04%3A44%3A15IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-hal_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20catalytic%20properties%20of%20hierarchical%20micro/mesoporous%20materials%20based%20on%20FER%20zeolite&rft.jtitle=Microporous%20and%20mesoporous%20materials&rft.au=Khitev,%20Yu.P.&rft.date=2011-12-01&rft.volume=146&rft.issue=1&rft.spage=201&rft.epage=207&rft.pages=201-207&rft.issn=1387-1811&rft.eissn=1873-3093&rft_id=info:doi/10.1016/j.micromeso.2011.05.003&rft_dat=%3Chal_cross%3Eoai_HAL_hal_00645124v1%3C/hal_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_els_id=S138718111100223X&rfr_iscdi=true |