Infrared spectra of individual semiconducting single-walled carbon nanotubes: Testing the scaling of transition energies for large diameter nanotubes

We have measured the low-energy excitonic transitions of chiral assigned individual large-diameter semiconducting single-walled nanotubes using a high-resolution Fourier transform photoconductivity technique. When photoconductivity is complemented by Rayleigh scattering spectroscopy, as many as five...

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Veröffentlicht in:Physical review. B, Condensed matter and materials physics Condensed matter and materials physics, 2010-11, Vol.82 (19), Article 195424
Hauptverfasser: Sfeir, Matthew Y., Misewich, James A., Rosenblatt, Sami, Wu, Yang, Voisin, Christophe, Yan, Hugen, Berciaud, Stéphane, Heinz, Tony F., Chandra, Bhupesh, Caldwell, Robert, Shan, Yuyao, Hone, James, Carr, G. L.
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container_issue 19
container_start_page
container_title Physical review. B, Condensed matter and materials physics
container_volume 82
creator Sfeir, Matthew Y.
Misewich, James A.
Rosenblatt, Sami
Wu, Yang
Voisin, Christophe
Yan, Hugen
Berciaud, Stéphane
Heinz, Tony F.
Chandra, Bhupesh
Caldwell, Robert
Shan, Yuyao
Hone, James
Carr, G. L.
description We have measured the low-energy excitonic transitions of chiral assigned individual large-diameter semiconducting single-walled nanotubes using a high-resolution Fourier transform photoconductivity technique. When photoconductivity is complemented by Rayleigh scattering spectroscopy, as many as five optical transitions can be identified on the same individual nanotube over an energy range of 0.3-2.7 eV. We find that well-established energy scaling relations developed for nanotubes of smaller diameter are not consistent with the measured low-energy transitions in large (1.8-2.3 nm) diameter nanotubes.
doi_str_mv 10.1103/PhysRevB.82.195424
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Other
Physics
title Infrared spectra of individual semiconducting single-walled carbon nanotubes: Testing the scaling of transition energies for large diameter nanotubes
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