Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(II) anthracenophane
Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(II) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are antiferromagnetically coupled in the dicopper(II) metallacyclic precursor (ON state) bec...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (39), p.11035-11037 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 47 |
| creator | Castellano, María Ferrando-Soria, Jesús Pardo, Emilio Julve, Miguel Lloret, Francesc Mathonière, Corine Pasán, Jorge Ruiz-Pérez, Catalina Cañadillas-Delgado, Laura Ruiz-García, Rafael Cano, Joan |
| description | Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(II) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are antiferromagnetically coupled in the dicopper(II) metallacyclic precursor (ON state) become uncoupled in the corresponding [4+4] photocycloaddition product (OFF state), as substantiated from both experimental and theoretical studies. |
| doi_str_mv | 10.1039/c1cc15087a |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2011-01, Vol.47 (39), p.11035-11037 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Antiferromagnetism Chemical Sciences Heating Joining Light irradiation Material chemistry Precursors Switching |
| title | Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(II) anthracenophane |
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