Chiral-at-ansa-Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6-tBu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization

New chiral racemic, sterically crowded fluorenyl-cyclopentadienyl compounds having monoaryl-substituted methylene bridges (R1R2C)-((3,6-tBu2Flu)H)(3-R3-5-Me-C5H3) (R1 = H, R2 = Ph, R3 = tBu: 2a; R1 = H, R2 = 2,4,6-Me3C6H2 (Mes); R3 = CMe2Ph (cumyl): 2b; R1 = H, R2 = 3,5-(CF3)2C6H3, R3 = tBu: 2c) or...

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Veröffentlicht in:	Organometallics 2011-01, Vol.30 (2), p.263-272
Hauptverfasser:	Kirillov, Evgeny, Marquet, Nicolas, Bader, Manuela, Razavi, Abbas, Belia, Vincenzo, Hampel, Frank, Roisnel, Thierry, Gladysz, John A, Carpentier, Jean-François
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences
Online-Zugang:	Volltext
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