Enhanced hydrogen release by catalyzed hydrolysis of sodium borohydride-ammonia borane mixtures: a solution-state B-11 NMR study

Hydrolysis of mixtures consisting of sodium borohydride NaBH4 (SB) and ammonia borane NH3BH3 (AB) was studied in the absence/presence of a Co catalyst. The kinetics of the H-2 evolutions was measured. The reactions were followed in situ by solution-state B-11 NMR and the hydrolysis by-products chara...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2011, Vol.13, p.3809-3818
Hauptverfasser: Hannauer, J., Demirci, U. B., Geantet, C., Herrmann, J. M. Null, Miele, P.
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Sprache:eng
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