Mechanistic Aspects of Polynaphthalimide Synthesis from NMR Analysis

Mechanistic Aspects of Polynaphthalimide Synthesis from NMR Analysis

The mechanism of the polycondensation reaction leading to naphthalimide polymers has been investigated using a model compound. In complement to 19F-NMR analysis, 1H- and 13C-NMR spectroscopies were used to identify the intermediate compound. It was concluded that there was no evidence for the format...

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Veröffentlicht in:High performance polymers 2009-10, Vol.21 (5), p.624-632
Hauptverfasser: Piroux, Fabienne, Mercier, Regis, Picq, Dominique
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Polymers
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creator Piroux, Fabienne
Mercier, Regis
Picq, Dominique
description The mechanism of the polycondensation reaction leading to naphthalimide polymers has been investigated using a model compound. In complement to 19F-NMR analysis, 1H- and 13C-NMR spectroscopies were used to identify the intermediate compound. It was concluded that there was no evidence for the formation of an isoimide, but the formation of an amide—acid intermediate was clearly demonstrated.
doi_str_mv 10.1177/0954008309339948
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title Mechanistic Aspects of Polynaphthalimide Synthesis from NMR Analysis
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