Copolyimides with trifluoromethyl or methoxy substituents. NMR characterization
In the first stage, a series of aromatic diamine compounds such as 2-methoxy-5,4′-diaminodiphenyl ether (ODAOMe) and 2-trifluomethyl-4,4′-diaminodiphenyl ether (ODACF 3) were synthesized. These aromatic diamines and 4,4′-diaminodiphenyl ether (ODA) were then used to prepare copolyimides with 4,4′-ox...
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| Veröffentlicht in: | Polymer (Guilford) 2002-03, Vol.43 (7), p.1983-1992 |
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| container_end_page | 1992 |
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| container_issue | 7 |
| container_start_page | 1983 |
| container_title | Polymer (Guilford) |
| container_volume | 43 |
| creator | Pinel, Eliette Bas, Corine Neyertz, Sylvie Albérola, N.Dominique Petiaud, Roger Mercier, Regis |
| description | In the first stage, a series of aromatic diamine compounds such as 2-methoxy-5,4′-diaminodiphenyl ether (ODAOMe) and 2-trifluomethyl-4,4′-diaminodiphenyl ether (ODACF
3) were synthesized. These aromatic diamines and 4,4′-diaminodiphenyl ether (ODA) were then used to prepare copolyimides with 4,4′-oxydiphthalic anhydride (ODPA) and bicyclo[2.2.2]-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA). Both chemical composition and the arrangements of repetitive units were characterized by
1H and
19F NMR. It was shown that solubility and thermal stability are related to the BCDA fraction in the copolymers and to the chemical structure of the diamine. |
| doi_str_mv | 10.1016/S0032-3861(02)00004-6 |
| format | Article |
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3) were synthesized. These aromatic diamines and 4,4′-diaminodiphenyl ether (ODA) were then used to prepare copolyimides with 4,4′-oxydiphthalic anhydride (ODPA) and bicyclo[2.2.2]-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA). Both chemical composition and the arrangements of repetitive units were characterized by
1H and
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3) were synthesized. These aromatic diamines and 4,4′-diaminodiphenyl ether (ODA) were then used to prepare copolyimides with 4,4′-oxydiphthalic anhydride (ODPA) and bicyclo[2.2.2]-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA). Both chemical composition and the arrangements of repetitive units were characterized by
1H and
19F NMR. It was shown that solubility and thermal stability are related to the BCDA fraction in the copolymers and to the chemical structure of the diamine.</description><subject>Alicyclic dianhydride</subject><subject>Applied sciences</subject><subject>Chemical Sciences</subject><subject>Copolymer synthesis</subject><subject>Exact sciences and technology</subject><subject>NMR characterization</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymers</subject><subject>Polymers with particular properties</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEQx4MoWKsfQdiLYA9b89js4ySlqBWqBR_nMJtN2Mh2U5K0Wj-9u63Uo3OZB7__DPNH6JLgMcEkvXnFmNGY5Sm5xnSEu0ji9AgNSJ6xmNKCHKPBATlFZ95_dAzlNBmgxdSubLM1S1MpH32aUEfBGd2srbNLFeptE1kX9ZX92kZ-Xfpgwlq1wY-j56eXSNbgQAblzDcEY9tzdKKh8eriNw_R-_3d23QWzxcPj9PJPJYsIyFOJU3yknPMKs0TAA6FzqiUOWZagSplUmaQSc0LXWYMKp6lFS1KqqnumhzYEI32e2toxMqZJbitsGDEbDIX_QxjzvOMJBvSsXzPSme9d0ofBASL3kGxc1D09ghMxc5BkXa6q71uBV5Cox200vg_MUvSpEh77nbPqe7hjVFOeGlUK1VlnJJBVNb8c-kHnkaG3g</recordid><startdate>20020301</startdate><enddate>20020301</enddate><creator>Pinel, Eliette</creator><creator>Bas, Corine</creator><creator>Neyertz, Sylvie</creator><creator>Albérola, N.Dominique</creator><creator>Petiaud, Roger</creator><creator>Mercier, Regis</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-0914-6287</orcidid></search><sort><creationdate>20020301</creationdate><title>Copolyimides with trifluoromethyl or methoxy substituents. NMR characterization</title><author>Pinel, Eliette ; Bas, Corine ; Neyertz, Sylvie ; Albérola, N.Dominique ; Petiaud, Roger ; Mercier, Regis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c371t-6c248b5503df54aa5a9f72cc803feaebc4b7a7cf59fb73ad576d29b2f2fad58a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Alicyclic dianhydride</topic><topic>Applied sciences</topic><topic>Chemical Sciences</topic><topic>Copolymer synthesis</topic><topic>Exact sciences and technology</topic><topic>NMR characterization</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymers</topic><topic>Polymers with particular properties</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pinel, Eliette</creatorcontrib><creatorcontrib>Bas, Corine</creatorcontrib><creatorcontrib>Neyertz, Sylvie</creatorcontrib><creatorcontrib>Albérola, N.Dominique</creatorcontrib><creatorcontrib>Petiaud, Roger</creatorcontrib><creatorcontrib>Mercier, Regis</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Polymer (Guilford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pinel, Eliette</au><au>Bas, Corine</au><au>Neyertz, Sylvie</au><au>Albérola, N.Dominique</au><au>Petiaud, Roger</au><au>Mercier, Regis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolyimides with trifluoromethyl or methoxy substituents. NMR characterization</atitle><jtitle>Polymer (Guilford)</jtitle><date>2002-03-01</date><risdate>2002</risdate><volume>43</volume><issue>7</issue><spage>1983</spage><epage>1992</epage><pages>1983-1992</pages><issn>0032-3861</issn><eissn>1873-2291</eissn><coden>POLMAG</coden><abstract>In the first stage, a series of aromatic diamine compounds such as 2-methoxy-5,4′-diaminodiphenyl ether (ODAOMe) and 2-trifluomethyl-4,4′-diaminodiphenyl ether (ODACF
3) were synthesized. These aromatic diamines and 4,4′-diaminodiphenyl ether (ODA) were then used to prepare copolyimides with 4,4′-oxydiphthalic anhydride (ODPA) and bicyclo[2.2.2]-oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA). Both chemical composition and the arrangements of repetitive units were characterized by
1H and
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| ispartof | Polymer (Guilford), 2002-03, Vol.43 (7), p.1983-1992 |
| issn | 0032-3861 1873-2291 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Alicyclic dianhydride Applied sciences Chemical Sciences Copolymer synthesis Exact sciences and technology NMR characterization Organic polymers Physicochemistry of polymers Polymers Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Copolyimides with trifluoromethyl or methoxy substituents. NMR characterization |
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