Oxidation of methane and ethylene in water at ambient conditions

Available spectroscopic, labelling and reactivity data show that stable μ-nitrido diiron phthalocyanine activates H 2O 2 to form a high-valent diiron oxo species. This species is a very powerful oxidant which oxidizes methane in pure water at 25–60 °C to methanol, formaldehyde and formic acid. The c...

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Veröffentlicht in:	Catalysis today 2010-11, Vol.157 (1), p.149-154
Hauptverfasser:	Sorokin, A.B., Kudrik, E.V., Alvarez, L.X., Afanasiev, P., Millet, J.M.M., Bouchu, D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Chemistry Environment and Society Environmental Sciences Ethylene Exact sciences and technology General and physical chemistry Hydrogen peroxide Iron Methane Oxidation Phthalocyanine Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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