Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines

Multiconfigurational, intermediate valent ground states are established in several methyl-substituted bipyridine complexes of bis(pentamethylcyclopentadienyl)ytterbium, Cp2 *Yb (Me x -bipy). In contrast to Cp2 *Yb(bipy) and other substituted-bipy complexes, the nature of both the ground state and th...

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Veröffentlicht in:	Journal of the American Chemical Society 2010-12, Vol.132 (49), p.17537-17549
Hauptverfasser:	Booth, Corwin H, Kazhdan, Daniel, Werkema, Evan L, Walter, Marc D, Lukens, Wayne W, Bauer, Eric D, Hu, Yung-Jin, Maron, Laurent, Eisenstein, Odile, Head-Gordon, Martin, Andersen, Richard A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Inorganic chemistry or physical chemistry Theoretical and
Online-Zugang:	Volltext
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