A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2]·3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazole

A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2]·3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazole

In order to assemble polynuclear iron(III) complexes, the coordination chemistry of the 2-hydroxyethyl- 3,5-dimethylpyrazole (hedmp-H) ligand has been investigated. Reaction of hedmp-H with trinuclear iron carboxylate precursor [Fe3O(PhCOO)6(H2O)3]Cl in acetonitrile yielded the hexanuclear Fe(III) c...

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Veröffentlicht in:Inorganica Chimica Acta 2010-10, Vol.363 (12), p.3004-3009
Hauptverfasser: Murugavel, Ramaswamy, Gogoi, Nayanmoni, Howlader, Rana, Clérac, Rodolphe
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Inorganic chemistry
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container_issue 12
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container_title Inorganica Chimica Acta
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creator Murugavel, Ramaswamy
Gogoi, Nayanmoni
Howlader, Rana
Clérac, Rodolphe
description In order to assemble polynuclear iron(III) complexes, the coordination chemistry of the 2-hydroxyethyl- 3,5-dimethylpyrazole (hedmp-H) ligand has been investigated. Reaction of hedmp-H with trinuclear iron carboxylate precursor [Fe3O(PhCOO)6(H2O)3]Cl in acetonitrile yielded the hexanuclear Fe(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2].3CH3CN (1). This aggregate has been characterized by employing various analytical techniques, spectroscopic studies and single crystal X-ray diffraction. Detailed magnetic susceptibility measurements revealed that 1 displays an ST = 5 ground state.
doi_str_mv 10.1016/j.ica.2010.03.034
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title A hexanuclear iron(III) complex [Fe6O2(OH)2(PhCOO)10(hedmp)2]·3CH3CN assembled from 2-hydroxyethyl-3,5-dimethyl pyrazole
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