Amorphous/nanocrystalline composites analysed by the Rietveld method

The Rietveld refinement approach has been applied to semi-crystalline materials in the case of bulk metallic glasses. Specifically, the crystallisation behaviour of a Fe 48Cr 15Mo 14Y 2C 15B 6 bulk metallic glass has been investigated by in situ X-ray diffraction obtained using a high intensity mono...

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Veröffentlicht in:Journal of alloys and compounds 2010-04, Vol.495 (2), p.377-381
Hauptverfasser: Baricco, M., Enzo, S., Baser, T.A., Satta, M., Vaughan, G., Yavari, A.R.
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container_end_page 381
container_issue 2
container_start_page 377
container_title Journal of alloys and compounds
container_volume 495
creator Baricco, M.
Enzo, S.
Baser, T.A.
Satta, M.
Vaughan, G.
Yavari, A.R.
description The Rietveld refinement approach has been applied to semi-crystalline materials in the case of bulk metallic glasses. Specifically, the crystallisation behaviour of a Fe 48Cr 15Mo 14Y 2C 15B 6 bulk metallic glass has been investigated by in situ X-ray diffraction obtained using a high intensity monochromatic synchrotron beam at the ID11 line of ESRF in Grenoble, France. From the Rietveld analysis of diffraction patterns, adapted to include a paracrystal model for describing the amorphous metal component, volume fraction of evolving phases, structure and microstructure parameters of nucleated phases have been followed as a function of run number, which turns out to be related to the applied temperature. Capabilities and limitations of the approach are discussed in terms of structural information.
doi_str_mv 10.1016/j.jallcom.2009.11.024
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source ScienceDirect Journals (5 years ago - present)
subjects Amorphous materials
Beams (radiation)
Chemical Sciences
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Crystal structure
Crystallization
Diffraction
Disordered solids
Exact sciences and technology
Glasses
Growth from solid phases (including multiphase diffusion and recrystallization)
Material chemistry
Materials science
Mathematical models
Metallic glasses
Methods of crystal growth
physics of crystal growth
Phases
Physics
Quenching
Rapid-solidification
Structure of solids and liquids
crystallography
Synchrotrons
X-ray diffraction
title Amorphous/nanocrystalline composites analysed by the Rietveld method
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