Synthesis of Ultrathin Hexagonal Palladium Nanosheets

Synthesis of Ultrathin Hexagonal Palladium Nanosheets

Ultrathin palladium hexagonal nanosheets were synthesized in emulsions constituted of droplets of toluene containing Pd complexes in water and stabilized by CTAB as surfactant and in quaternary mesophases formed by water, toluene containing Pd complexes, CTAB, and a cosurfactant. We have identified...

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Veröffentlicht in:Chemistry of materials 2009-11, Vol.21 (21), p.5170-5175
Hauptverfasser: Siril, Prem F, Ramos, Laurence, Beaunier, Patricia, Archirel, Pierre, Etcheberry, Arnaud, Remita, Hynd
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Chemical Sciences
Liquid Crystals
Material chemistry
Nanomaterials (Nanops, Nanotubes, etc.)
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container_end_page 5175
container_issue 21
container_start_page 5170
container_title Chemistry of materials
container_volume 21
creator Siril, Prem F
Ramos, Laurence
Beaunier, Patricia
Archirel, Pierre
Etcheberry, Arnaud
Remita, Hynd
description Ultrathin palladium hexagonal nanosheets were synthesized in emulsions constituted of droplets of toluene containing Pd complexes in water and stabilized by CTAB as surfactant and in quaternary mesophases formed by water, toluene containing Pd complexes, CTAB, and a cosurfactant. We have identified slow reduction and nucleation provided by CO and adsorption at the CTAB interface as key factors for the formation of Pd nanosheets. These nanosheets exhibit a broad absorption band from the visible to the near-infrared region.
doi_str_mv 10.1021/cm9021134
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Liquid Crystals
Material chemistry
Nanomaterials (Nanops, Nanotubes, etc.)
title Synthesis of Ultrathin Hexagonal Palladium Nanosheets
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