Green chemicals and process to graft cellulose fibers
The treatment of additive-free hand sheet paper samples with cold plasma was carried out and showed that cellulose can be chemically linked with reactive natural products, namely myrcene (My) and limonene (LM). Contact-angle measurement and X-ray photoelectron spectroscopy (XPS) were used to ascerta...
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| Veröffentlicht in: | Journal of colloid and interface science 2009-02, Vol.330 (2), p.298-302 |
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| container_title | Journal of colloid and interface science |
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| creator | Gaiolas, Carla Belgacem, Mohamed Naceur Silva, Lúcia Thielemans, Wim Costa, Ana Paula Nunes, Mario Santos Silva, Manuel José |
| description | The treatment of additive-free hand sheet paper samples with cold plasma was carried out and showed that cellulose can be chemically linked with reactive natural products, namely myrcene (My) and limonene (LM). Contact-angle measurement and X-ray photoelectron spectroscopy (XPS) were used to ascertain the occurrence of the grafting. Indeed, the contact-angle value of a drop of water deposited at the surface of paper increased from 30° for unmodified substrate to about 105 and 107°, for LM- and My-treated samples, respectively. In fact, LM- and My-treated surfaces were rendered totally apolar. Indeed, the polar contribution to the surface energy decreased from about 23 mJ/m
2 for pristine samples to practically zero for treated ones. The treated surfaces displayed water-barrier properties; the penetration of the liquid was reduced significantly after LM and My treatments. The XPS spectra showed that the modification with LM and My gave rise to very significant change in the O/C ratio, as well as in the intensity of the C1 peak assigned to aliphatic carbon sequences. |
| doi_str_mv | 10.1016/j.jcis.2008.10.059 |
| format | Article |
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2 for pristine samples to practically zero for treated ones. The treated surfaces displayed water-barrier properties; the penetration of the liquid was reduced significantly after LM and My treatments. The XPS spectra showed that the modification with LM and My gave rise to very significant change in the O/C ratio, as well as in the intensity of the C1 peak assigned to aliphatic carbon sequences.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2008.10.059</identifier><identifier>PMID: 19027124</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Chemical and Process Engineering ; Chemistry ; Cold plasma ; Colloidal state and disperse state ; Coupling agents ; Engineering Sciences ; Exact sciences and technology ; General and physical chemistry ; Surface physical chemistry ; Terpenes ; Wettability ; XPS</subject><ispartof>Journal of colloid and interface science, 2009-02, Vol.330 (2), p.298-302</ispartof><rights>2008 Elsevier Inc.</rights><rights>2009 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c418t-b50f9ffb7fb96233fa8dcc64b85e596342006dd43498b7b5e21e53799dc8457d3</citedby><cites>FETCH-LOGICAL-c418t-b50f9ffb7fb96233fa8dcc64b85e596342006dd43498b7b5e21e53799dc8457d3</cites><orcidid>0000-0003-3788-878X ; 0000-0002-3317-7369 ; 0000-0003-4451-1964</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0021979708013908$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21167424$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19027124$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00511765$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Gaiolas, Carla</creatorcontrib><creatorcontrib>Belgacem, Mohamed Naceur</creatorcontrib><creatorcontrib>Silva, Lúcia</creatorcontrib><creatorcontrib>Thielemans, Wim</creatorcontrib><creatorcontrib>Costa, Ana Paula</creatorcontrib><creatorcontrib>Nunes, Mario</creatorcontrib><creatorcontrib>Santos Silva, Manuel José</creatorcontrib><title>Green chemicals and process to graft cellulose fibers</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>The treatment of additive-free hand sheet paper samples with cold plasma was carried out and showed that cellulose can be chemically linked with reactive natural products, namely myrcene (My) and limonene (LM). Contact-angle measurement and X-ray photoelectron spectroscopy (XPS) were used to ascertain the occurrence of the grafting. Indeed, the contact-angle value of a drop of water deposited at the surface of paper increased from 30° for unmodified substrate to about 105 and 107°, for LM- and My-treated samples, respectively. In fact, LM- and My-treated surfaces were rendered totally apolar. Indeed, the polar contribution to the surface energy decreased from about 23 mJ/m
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Contact-angle measurement and X-ray photoelectron spectroscopy (XPS) were used to ascertain the occurrence of the grafting. Indeed, the contact-angle value of a drop of water deposited at the surface of paper increased from 30° for unmodified substrate to about 105 and 107°, for LM- and My-treated samples, respectively. In fact, LM- and My-treated surfaces were rendered totally apolar. Indeed, the polar contribution to the surface energy decreased from about 23 mJ/m
2 for pristine samples to practically zero for treated ones. The treated surfaces displayed water-barrier properties; the penetration of the liquid was reduced significantly after LM and My treatments. The XPS spectra showed that the modification with LM and My gave rise to very significant change in the O/C ratio, as well as in the intensity of the C1 peak assigned to aliphatic carbon sequences.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>19027124</pmid><doi>10.1016/j.jcis.2008.10.059</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3788-878X</orcidid><orcidid>https://orcid.org/0000-0002-3317-7369</orcidid><orcidid>https://orcid.org/0000-0003-4451-1964</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Chemical and Process Engineering Chemistry Cold plasma Colloidal state and disperse state Coupling agents Engineering Sciences Exact sciences and technology General and physical chemistry Surface physical chemistry Terpenes Wettability XPS |
| title | Green chemicals and process to graft cellulose fibers |
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