Volumetric Properties of Mono-, Di-, Tri-, and Polyethylene Glycol Aqueous Solutions from (273.15 to 363.15) K: Experimental Measurements and Correlations
Densities and excess molar volume data for various glycol (mono-, di-, tri-, and polyethylene glycol-400) aqueous solutions have been measured over wide ranges of compositions and temperatures generally from (273.15 to 363.15) K at atmospheric pressure. All the measurements were performed using a di...
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Veröffentlicht in: | Journal of chemical and engineering data 2009-04, Vol.54 (4), p.1254-1261 |
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description | Densities and excess molar volume data for various glycol (mono-, di-, tri-, and polyethylene glycol-400) aqueous solutions have been measured over wide ranges of compositions and temperatures generally from (273.15 to 363.15) K at atmospheric pressure. All the measurements were performed using a digital vibrating tube densimeter. Densities of mono-, di-, and triethylene glycol in pure form and those of polyethylene glycol (400) are correlated using the Daubert et al. correlation. Excess molar volumes of glycol aqueous solutions have been correlated with mole fraction polynomials. For all the studied systems, excess molar volumes are found to be negative, increasing from monoethylene glycol to polyethylene glycol-400. |
doi_str_mv | 10.1021/je800694a |
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All the measurements were performed using a digital vibrating tube densimeter. Densities of mono-, di-, and triethylene glycol in pure form and those of polyethylene glycol (400) are correlated using the Daubert et al. correlation. Excess molar volumes of glycol aqueous solutions have been correlated with mole fraction polynomials. 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Chem. Eng. Data</addtitle><description>Densities and excess molar volume data for various glycol (mono-, di-, tri-, and polyethylene glycol-400) aqueous solutions have been measured over wide ranges of compositions and temperatures generally from (273.15 to 363.15) K at atmospheric pressure. All the measurements were performed using a digital vibrating tube densimeter. Densities of mono-, di-, and triethylene glycol in pure form and those of polyethylene glycol (400) are correlated using the Daubert et al. correlation. Excess molar volumes of glycol aqueous solutions have been correlated with mole fraction polynomials. For all the studied systems, excess molar volumes are found to be negative, increasing from monoethylene glycol to polyethylene glycol-400.</description><subject>Applied sciences</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Engineering Sciences</subject><subject>Exact sciences and technology</subject><subject>Fluid mechanics</subject><subject>Fluids mechanics</subject><subject>General and physical chemistry</subject><subject>Mechanics</subject><subject>Mixtures</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Physics</subject><subject>Properties and characterization</subject><subject>Thermal and thermodynamic properties</subject><subject>Thermodynamic properties</subject><issn>0021-9568</issn><issn>1520-5134</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNptkU1v2zAMhoWhA5Z2O-wf6DJgBeaWsj5s9xZk_UJTrMC6XQ1GplAHipVK9rD8lf7a2u2QXnYhRfJ9H0kgY58FnAjIxemaSgBTKXzHZkLnkGkh1QGbwTjMKm3KD-wwpTUAqCIXM_b0O_hhQ31sLb-LYUuxbynx4Pht6EL2jX9vx3Afp4hdw--C31H_sPPUEb_0Oxs8nz8OFIbEf46ovg1d4i6GDf-aF_JEaN4HLs10OuY3Z_z873hHu6GuR89vCdMQaarSC34RYiSPL5SP7L1Dn-jTv3zEfl2c3y-usuWPy-vFfJmhLKs-I-FW0mgiJQuHiE5RA6ppsKRipUVh5KqxWhDklVCOpCVlwZQrU4IAOY6P2PEr9wF9vR3fhnFXB2zrq_mynnoAGioj1B_xprUxpBTJ7Q0C6mkB9X4Bo_bLq3aLyaJ3ETvbpr0hF1KXBsSbDm2q12GI3fjb__CeAalfj-E</recordid><startdate>20090409</startdate><enddate>20090409</enddate><creator>Afzal, Waheed</creator><creator>Mohammadi, Amir H.</creator><creator>Richon, Dominique</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope></search><sort><creationdate>20090409</creationdate><title>Volumetric Properties of Mono-, Di-, Tri-, and Polyethylene Glycol Aqueous Solutions from (273.15 to 363.15) K: Experimental Measurements and Correlations</title><author>Afzal, Waheed ; Mohammadi, Amir H. ; Richon, Dominique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a389t-e1fb365ee437faaaf4ed04dda8e7b51763bdc51e02914fe3ce4c068b680103763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Engineering Sciences</topic><topic>Exact sciences and technology</topic><topic>Fluid mechanics</topic><topic>Fluids mechanics</topic><topic>General and physical chemistry</topic><topic>Mechanics</topic><topic>Mixtures</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Physics</topic><topic>Properties and characterization</topic><topic>Thermal and thermodynamic properties</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Afzal, Waheed</creatorcontrib><creatorcontrib>Mohammadi, Amir H.</creatorcontrib><creatorcontrib>Richon, Dominique</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of chemical and engineering data</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Afzal, Waheed</au><au>Mohammadi, Amir H.</au><au>Richon, Dominique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Volumetric Properties of Mono-, Di-, Tri-, and Polyethylene Glycol Aqueous Solutions from (273.15 to 363.15) K: Experimental Measurements and Correlations</atitle><jtitle>Journal of chemical and engineering data</jtitle><addtitle>J. Chem. Eng. Data</addtitle><date>2009-04-09</date><risdate>2009</risdate><volume>54</volume><issue>4</issue><spage>1254</spage><epage>1261</epage><pages>1254-1261</pages><issn>0021-9568</issn><eissn>1520-5134</eissn><coden>JCEAAX</coden><abstract>Densities and excess molar volume data for various glycol (mono-, di-, tri-, and polyethylene glycol-400) aqueous solutions have been measured over wide ranges of compositions and temperatures generally from (273.15 to 363.15) K at atmospheric pressure. All the measurements were performed using a digital vibrating tube densimeter. Densities of mono-, di-, and triethylene glycol in pure form and those of polyethylene glycol (400) are correlated using the Daubert et al. correlation. Excess molar volumes of glycol aqueous solutions have been correlated with mole fraction polynomials. For all the studied systems, excess molar volumes are found to be negative, increasing from monoethylene glycol to polyethylene glycol-400.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/je800694a</doi><tpages>8</tpages></addata></record> |
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subjects | Applied sciences Chemical thermodynamics Chemistry Engineering Sciences Exact sciences and technology Fluid mechanics Fluids mechanics General and physical chemistry Mechanics Mixtures Organic polymers Physicochemistry of polymers Physics Properties and characterization Thermal and thermodynamic properties Thermodynamic properties |
title | Volumetric Properties of Mono-, Di-, Tri-, and Polyethylene Glycol Aqueous Solutions from (273.15 to 363.15) K: Experimental Measurements and Correlations |
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