MNα Cycloaddition and Nα−Nβ Insertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study

A combined experimental and DFT study of the reactions of diamide-amine supported titanium hydrazides with alkynes is presented. Reaction of Ti(N2Npy)(NNPh2)(py) (1, N2Npy = (2-NC5H4)CMe(CH2NSiMe3)2) with terminal and internal aryl alkynes ArCCR (Ar = Ph or substituted phenyl, R = Me or H) at room t...

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Veröffentlicht in:	Journal of the American Chemical Society 2010-08, Vol.132 (30), p.10484-10497
Hauptverfasser:	Schofield, A. Daniel, Nova, Ainara, Selby, Jonathan D, Manley, Catherine D, Schwarz, Andrew D, Clot, Eric, Mountford, Philip
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences or physical chemistry Theoretical and
Online-Zugang:	Volltext
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