Tri-, Tetra-, and Hexanuclear Copper(II) Phosphonates Containing N-Donor Chelating Ligands: Synthesis, Structure, Magnetic Properties, and Nuclease Activity

Reaction of Cu(ClO4)2·6H2O with cyclopentyl phosphonic acid and 2,2′-bipyridine (bpy) in presence of triethylamine afforded a trinuclear compound [Cu3(C5H9PO3)2(bpy)3(MeOH)(H2O)](ClO4)2 (2). The latter dimerizes to a hexanuclear derivative [Cu6(C5H9PO3)4(bpy)6(MeOH)4](ClO4)4 (1) under prolonged reac...

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Veröffentlicht in:	Inorganic chemistry 2009-07, Vol.48 (13), p.6192-6204
Hauptverfasser:	Chandrasekhar, Vadapalli, Senapati, Tapas, Sañudo, E. Carolina, Clérac, R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelating Agents - chemistry Chemical Sciences Coordination chemistry Copper - chemistry Crystallography, X-Ray Ligands Magnetics Material chemistry Molecular Structure Organophosphonates - chemical synthesis Organophosphonates - chemistry Spectrometry, Mass, Electrospray Ionization Spectroscopy, Fourier Transform Infrared
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