First Titanium-Catalyzed 1,4-Hydrophosphination of 1,3-Dienes

Titanium complexes outshine other catalysts: Titanium complexes have been found to catalyze 1,4‐hydrophosphination of dienes, which is thought to proceed through an allyl intermediate (see scheme). Unprecedented regioselectivities (1,4‐ vs. 1,2‐) are reached by using [TiCp2(PMe3)2] or a titanocene c...

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Veröffentlicht in:	Chemistry : a European journal 2010-01, Vol.16 (1), p.64-67
Hauptverfasser:	Perrier, Arnaud, Comte, Virginie, Moïse, Claude, Le Gendre, Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Bearing Catalysis Catalysts Chemical Sciences Chemistry Dienes homogeneous catalysis hydrophosphination Jewelry Phosphines Tethers Titanium
Online-Zugang:	Volltext
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