Reactions of dicarbanion equivalents generated from complexation of 1,3-dienes on Ti(II) moiety

Conjugated dienes are able to react as 1,2- or 1,4-dicarbanions by coordination on Ti(II) moiety. These two possibilities are exemplified in this letter with isoprene, myrcene and several aldehydes to give 1,4- and 1,6-diols. When allowed to react with esters at room temperature, the titanium–diene...

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Veröffentlicht in:	Tetrahedron letters 2006-11, Vol.47 (47), p.8319-8322
Hauptverfasser:	Baraut, Johann, Perrier, Arnaud, Comte, Virginie, Richard, Philippe, Le Gendre, Pierre, Moïse, Claude
Format:	Artikel
Sprache:	eng
Schlagworte:	Allylic ketone Chemical Sciences Coordination chemistry Cyclopentenol Diene Diol Titanium
Online-Zugang:	Volltext
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