Role of nascent metallic surfaces on the tribochemistry of phosphite lubricant additives
The role of the nascent surface on the decomposition of phosphite additives has been investigated. An environmentally controlled tribometer was used to conduct tribotest in UHV and gas. Sliding test in UHV was performed to tribo-activate steel surfaces. Adsorption of trimethylphosphite on tribo-acti...
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| Veröffentlicht in: | Tribology international 2011-06, Vol.44 (6), p.684-691 |
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| container_title | Tribology international |
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| creator | Philippon, D. De Barros-Bouchet, M.-I. Le Mogne, Th Lerasle, O. Bouffet, A. Martin, J.-M. |
| description | The role of the nascent surface on the decomposition of phosphite additives has been investigated. An environmentally controlled tribometer was used to conduct tribotest in UHV and gas. Sliding test in UHV was performed to tribo-activate steel surfaces. Adsorption of trimethylphosphite on tribo-activated surface was made to investigate its decomposition on freshly scratched surfaces.
In situ XPS analyses have shown that tribofilm of iron phosphide is poorly formed on the tribo-activated surface. This observation confirms that iron phosphide tribofilm is mainly formed under tribological condition. The role of the contact pressure and tribo-emission process is highlighted. |
| doi_str_mv | 10.1016/j.triboint.2009.12.014 |
| format | Article |
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In situ XPS analyses have shown that tribofilm of iron phosphide is poorly formed on the tribo-activated surface. This observation confirms that iron phosphide tribofilm is mainly formed under tribological condition. The role of the contact pressure and tribo-emission process is highlighted.</description><subject>Applied sciences</subject><subject>Contact of materials. Friction. Wear</subject><subject>Contact pressure</subject><subject>Decomposition</subject><subject>Engineering Sciences</subject><subject>Environmental tribometer</subject><subject>Exact sciences and technology</subject><subject>Friction, wear, lubrication</subject><subject>In situ XPS</subject><subject>Machine components</subject><subject>Materials</subject><subject>Mechanical engineering. Machine design</subject><subject>Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology</subject><subject>Metals. Metallurgy</subject><subject>Nascent surface</subject><subject>Phosphides</subject><subject>Phosphite additives</subject><subject>Steels</subject><subject>Surface chemistry</subject><subject>Tribology</subject><subject>Tribometers</subject><subject>X-ray photoelectron spectroscopy</subject><issn>0301-679X</issn><issn>1879-2464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkF1LHDEUhkOx0K31L8jciPRixnztTOZOkVaFBaG04F04k5xhsmQna5Jd8N8366q3XgUOz_u-5CHknNGGUdZerZsc3RDcnBtOad8w3lAmv5AFU11fc9nKE7KggrK67fqnb-R7SmtKaSf7bkGe_gSPVRirGZLBOVcbzOC9M1XaxREMpirMVZ6weh0xE25cyvHlENlOIW0nl7HyuyE6AyUO1rrs9ph-kK8j-IRnb-8p-ff719_b-3r1ePdwe7OqjaQq12qJ3AIIbgfBpYFh7HpuqLItArdsaVHwQdpWAVozLBkfW6p6IWDorLJdL07Jz2PvBF5vo9tAfNEBnL6_WenDjVLZCiHknhX28shuY3jeYcq6fMag9zBj2CWtSnPPGFeFbI-kiSGliONHNaP6YF2v9bt1fbCuGdfFeglevE0Un-DHCLNx6SPNJeuYosvCXR85LG72DqNOxuFs0LqIJmsb3GdT_wEEUZ1V</recordid><startdate>20110601</startdate><enddate>20110601</enddate><creator>Philippon, D.</creator><creator>De Barros-Bouchet, M.-I.</creator><creator>Le Mogne, Th</creator><creator>Lerasle, O.</creator><creator>Bouffet, A.</creator><creator>Martin, J.-M.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-0345-5687</orcidid><orcidid>https://orcid.org/0000-0002-3362-8633</orcidid><orcidid>https://orcid.org/0000-0002-3873-5470</orcidid></search><sort><creationdate>20110601</creationdate><title>Role of nascent metallic surfaces on the tribochemistry of phosphite lubricant additives</title><author>Philippon, D. ; De Barros-Bouchet, M.-I. ; Le Mogne, Th ; Lerasle, O. ; Bouffet, A. ; Martin, J.-M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c408t-85e2daa32db324cabf792c08d6ea2d15de32b4d68aedcb512f608933ab7d8d793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>Contact of materials. 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An environmentally controlled tribometer was used to conduct tribotest in UHV and gas. Sliding test in UHV was performed to tribo-activate steel surfaces. Adsorption of trimethylphosphite on tribo-activated surface was made to investigate its decomposition on freshly scratched surfaces.
In situ XPS analyses have shown that tribofilm of iron phosphide is poorly formed on the tribo-activated surface. This observation confirms that iron phosphide tribofilm is mainly formed under tribological condition. The role of the contact pressure and tribo-emission process is highlighted.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.triboint.2009.12.014</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-0345-5687</orcidid><orcidid>https://orcid.org/0000-0002-3362-8633</orcidid><orcidid>https://orcid.org/0000-0002-3873-5470</orcidid></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Contact of materials. Friction. Wear Contact pressure Decomposition Engineering Sciences Environmental tribometer Exact sciences and technology Friction, wear, lubrication In situ XPS Machine components Materials Mechanical engineering. Machine design Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology Metals. Metallurgy Nascent surface Phosphides Phosphite additives Steels Surface chemistry Tribology Tribometers X-ray photoelectron spectroscopy |
| title | Role of nascent metallic surfaces on the tribochemistry of phosphite lubricant additives |
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