The photophysics and photochemistry of cofacial free base and metallated bisporphyrins held together by covalent architectures
This review focuses on the photophysical properties of bisporphyrin systems held in a face-to-face configuration by covalent bonds via flexible or rigid spacers and metal–metal bonds. The cofacial arrangement induces intramolecular bismacrocycle interactions promoting basic photophysical events such...
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| Veröffentlicht in: | Coordination chemistry reviews 2007-02, Vol.251 (3), p.401-428 |
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| container_end_page | 428 |
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| container_issue | 3 |
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| container_title | Coordination chemistry reviews |
| container_volume | 251 |
| creator | Harvey, Pierre D. Stern, Christine Gros, Claude P. Guilard, Roger |
| description | This review focuses on the photophysical properties of bisporphyrin systems held in a face-to-face configuration by covalent bonds via flexible or rigid spacers and metal–metal bonds. The cofacial arrangement induces intramolecular bismacrocycle interactions promoting basic photophysical events such as excitonic interactions and energy and electron transfers. These events are relevant to mimic light harvesting and reactor devices known for photosynthesis in plants, and can be monitored by luminescence and flash photolysis methods. |
| doi_str_mv | 10.1016/j.ccr.2006.06.009 |
| format | Article |
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| ispartof | Coordination chemistry reviews, 2007-02, Vol.251 (3), p.401-428 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals |
| subjects | Chemical Sciences Electron and energy transfer Emission Exciton Fluorescence Luminescence or physical chemistry Other Phosphorescence Photophysics Porphyrins Theoretical and |
| title | The photophysics and photochemistry of cofacial free base and metallated bisporphyrins held together by covalent architectures |
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