Zinc(II) complexes based on sterically hindered hydrotris(pyrazolyl)borate ligands: Synthesis, reactivity and solid-state structures

Zinc(II) complexes supported by Tp Ms and Tp Ms∗ ligands have been prepared and structurally characterized. The variable steric constraint around the zinc atom provided by the Tp Ms and Tp Ms∗ ligands is shown to have significant impacts, i.e., changes from monomeric to dimeric structures, and varia...

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Veröffentlicht in:Inorganica Chimica Acta 2009-09, Vol.362 (12), p.4585-4592
Hauptverfasser: Klitzke, Joice S., Roisnel, Thierry, Carpentier, Jean-François, Casagrande, Osvaldo L.
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Sprache:eng
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