Hydrostatic pressure investigation of the spin crossover compound [ Fe ( PM − BiA ) 2 ( NCS ) 2 ] polymorph I using reflectance detection
We investigated by diffuse reflectivity the effect of hydrostatic pressure (1-1800 bar) on the thermal spin transition of Fe ( PM − BiA ) 2 ( NCS ) 2 polymorph I, where PM = N - 2 -pyridylmethylene and BiA = 4 -aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of hig...
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| Veröffentlicht in: | Journal of applied physics 2009-09, Vol.106 (5), p.053515-053515-5 |
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| container_end_page | 053515-5 |
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| container_issue | 5 |
| container_start_page | 053515 |
| container_title | Journal of applied physics |
| container_volume | 106 |
| creator | Rotaru, Aurelian Varret, François Codjovi, Epiphane Boukheddaden, Kamel Linares, Jorge Stancu, Alexandru Guionneau, Philippe Létard, Jean-François |
| description | We investigated by diffuse reflectivity the effect of hydrostatic pressure (1-1800 bar) on the thermal spin transition of
Fe
(
PM
−
BiA
)
2
(
NCS
)
2
polymorph I, where
PM
=
N
-
2
-pyridylmethylene and
BiA
=
4
-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations. |
| doi_str_mv | 10.1063/1.3202385 |
| format | Article |
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Fe
(
PM
−
BiA
)
2
(
NCS
)
2
polymorph I, where
PM
=
N
-
2
-pyridylmethylene and
BiA
=
4
-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.3202385</identifier><identifier>CODEN: JAPIAU</identifier><language>eng</language><publisher>American Institute of Physics</publisher><subject>Chemical Sciences ; Material chemistry</subject><ispartof>Journal of applied physics, 2009-09, Vol.106 (5), p.053515-053515-5</ispartof><rights>2009 American Institute of Physics</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c419t-1712b6262cd6b4ea253c50d856b8feabd92309f24fea064075c203227dec75e23</citedby><cites>FETCH-LOGICAL-c419t-1712b6262cd6b4ea253c50d856b8feabd92309f24fea064075c203227dec75e23</cites><orcidid>0000-0003-4693-7715 ; 0000-0003-0464-1609</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/jap/article-lookup/doi/10.1063/1.3202385$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>230,314,780,784,794,885,1559,4512,27924,27925,76384,76390</link.rule.ids><backlink>$$Uhttps://hal.science/hal-00435071$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Rotaru, Aurelian</creatorcontrib><creatorcontrib>Varret, François</creatorcontrib><creatorcontrib>Codjovi, Epiphane</creatorcontrib><creatorcontrib>Boukheddaden, Kamel</creatorcontrib><creatorcontrib>Linares, Jorge</creatorcontrib><creatorcontrib>Stancu, Alexandru</creatorcontrib><creatorcontrib>Guionneau, Philippe</creatorcontrib><creatorcontrib>Létard, Jean-François</creatorcontrib><title>Hydrostatic pressure investigation of the spin crossover compound [ Fe ( PM − BiA ) 2 ( NCS ) 2 ] polymorph I using reflectance detection</title><title>Journal of applied physics</title><description>We investigated by diffuse reflectivity the effect of hydrostatic pressure (1-1800 bar) on the thermal spin transition of
Fe
(
PM
−
BiA
)
2
(
NCS
)
2
polymorph I, where
PM
=
N
-
2
-pyridylmethylene and
BiA
=
4
-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations.</description><subject>Chemical Sciences</subject><subject>Material chemistry</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNp1kMlOwzAQhi0EEqVw4A3mSA8pYzvOckEqFaWVyiIBJ4SixHFaozaOYrdS3wCJG4_Ik5AuLBdOHv_6Zsb-CDml2KUY8HPa5QwZj8QeaVGMYi8UAvdJC5FRL4rD-JAcWfuKSGnE4xZ5H67y2liXOi2hqpW1i1qBLpfKOj1pUlOCKcBNFdhKlyAb2JqlqkGaeWUWZQ7PMFBwBvc38Pn2AZe6Bx1gTXDbf9hUL1CZ2Wpu6moKI1hYXU6gVsVMSZeWUkGuXFM2i47JQZHOrDrZnW3yNLh67A-98d31qN8be9KnsfNoSFkWsIDJPMh8lTLBpcA8EkEWFSrN8phxjAvmNxcMfAyFZMgZC3MlQ6EYb5POdu40nSVVredpvUpMqpNhb5ysM0SfCwzpkv6ym483z_5poJisjSc02Rlv2Ista6V2G3X_w3-0J9_a-ReW1YeQ</recordid><startdate>20090901</startdate><enddate>20090901</enddate><creator>Rotaru, Aurelian</creator><creator>Varret, François</creator><creator>Codjovi, Epiphane</creator><creator>Boukheddaden, Kamel</creator><creator>Linares, Jorge</creator><creator>Stancu, Alexandru</creator><creator>Guionneau, Philippe</creator><creator>Létard, Jean-François</creator><general>American Institute of Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-4693-7715</orcidid><orcidid>https://orcid.org/0000-0003-0464-1609</orcidid></search><sort><creationdate>20090901</creationdate><title>Hydrostatic pressure investigation of the spin crossover compound [ Fe ( PM − BiA ) 2 ( NCS ) 2 ] polymorph I using reflectance detection</title><author>Rotaru, Aurelian ; Varret, François ; Codjovi, Epiphane ; Boukheddaden, Kamel ; Linares, Jorge ; Stancu, Alexandru ; Guionneau, Philippe ; Létard, Jean-François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c419t-1712b6262cd6b4ea253c50d856b8feabd92309f24fea064075c203227dec75e23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Chemical Sciences</topic><topic>Material chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rotaru, Aurelian</creatorcontrib><creatorcontrib>Varret, François</creatorcontrib><creatorcontrib>Codjovi, Epiphane</creatorcontrib><creatorcontrib>Boukheddaden, Kamel</creatorcontrib><creatorcontrib>Linares, Jorge</creatorcontrib><creatorcontrib>Stancu, Alexandru</creatorcontrib><creatorcontrib>Guionneau, Philippe</creatorcontrib><creatorcontrib>Létard, Jean-François</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rotaru, Aurelian</au><au>Varret, François</au><au>Codjovi, Epiphane</au><au>Boukheddaden, Kamel</au><au>Linares, Jorge</au><au>Stancu, Alexandru</au><au>Guionneau, Philippe</au><au>Létard, Jean-François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrostatic pressure investigation of the spin crossover compound [ Fe ( PM − BiA ) 2 ( NCS ) 2 ] polymorph I using reflectance detection</atitle><jtitle>Journal of applied physics</jtitle><date>2009-09-01</date><risdate>2009</risdate><volume>106</volume><issue>5</issue><spage>053515</spage><epage>053515-5</epage><pages>053515-053515-5</pages><issn>0021-8979</issn><eissn>1089-7550</eissn><coden>JAPIAU</coden><abstract>We investigated by diffuse reflectivity the effect of hydrostatic pressure (1-1800 bar) on the thermal spin transition of
Fe
(
PM
−
BiA
)
2
(
NCS
)
2
polymorph I, where
PM
=
N
-
2
-pyridylmethylene and
BiA
=
4
-aminobiphenyl. We evidenced the onset of a progressive transformation into a phase of higher cooperativity which cannot be assigned to polymorph II. This result is discussed with respect to previous pressure investigations.</abstract><pub>American Institute of Physics</pub><doi>10.1063/1.3202385</doi><orcidid>https://orcid.org/0000-0003-4693-7715</orcidid><orcidid>https://orcid.org/0000-0003-0464-1609</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8979 |
| ispartof | Journal of applied physics, 2009-09, Vol.106 (5), p.053515-053515-5 |
| issn | 0021-8979 1089-7550 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00435071v1 |
| source | AIP Journals Complete; AIP Digital Archive; Alma/SFX Local Collection |
| subjects | Chemical Sciences Material chemistry |
| title | Hydrostatic pressure investigation of the spin crossover compound [ Fe ( PM − BiA ) 2 ( NCS ) 2 ] polymorph I using reflectance detection |
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