Nitrogen-Based Chirality Effects in Novel Mixed Phosphorus/Nitrogen Ligands Applied to Palladium-Catalyzed Allylic Substitutions

A novel series of chiral P,N-ligands was obtained by desymmetrization of the achiral meso-N,N′-dimethyl-1,2-diphenylethane-1,2-diamine backbone and resolution of the resulting adducts. This transformation was achieved by the selective introduction of a diphenylphosphine moiety on one of the two nitr...

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Veröffentlicht in:	Organometallics 2008-11, Vol.27 (22), p.5997-6004
Hauptverfasser:	Schnitzler, Verena, Nonglaton, Guillaume, Roussière, Hélène, Maillet, Céline, Evain, Michel, Janvier, Pascal, Bujoli, Bruno, Petit, Marc
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed Matter Materials Science Physics
Online-Zugang:	Volltext
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