Reaction of H2 with IrHCl2P2 (P = PiPr3 or PtBu2Ph) : stereoelectronic control of the stability of molecular H2 transition metal complexes

IrHCl2P2 (P = PiPr3) reacts rapidly with H-2 at 25-degrees-C to set up an equilibrium where H-2 binds trans to the original hydride ligand (trans-2). A second slower reaction forms IrH(H2)Cl2P2 (cis-2), where the cis disposition of the chlorides, and also H cis to H-2, was established by neutron dif...

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Veröffentlicht in:	Journal of the American Chemical Society 1993-08, Vol.115 (16), p.7300-7312
Hauptverfasser:	ALBINATI, A, BAKHMUTOV, V. I, KOETZLE, T. F, MCMULLAN, R. K, O'LOUGHLIN, T. J, PELISSIER, M, RICCI, J. S, SIGALAS, M. P, VYMENITS, A. B, CAULTON, K. G, CLOT, E, ECKERT, J, EISENSTEIN, O, GUSEV, D. G, GRUSHIN, V. V, HAUGER, B. E, KLOOSTER, W. T
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Physics Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Kinetics and mechanism of reactions Metal complexes Physics Structure of solids and liquids crystallography Structure of specific crystalline solids
Online-Zugang:	Volltext
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