Influence of orthophosphate ions on the dissolution of tricalcium silicate

Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosph...

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Veröffentlicht in:Cement and concrete research 2008-10, Vol.38 (10), p.1137-1141
Hauptverfasser: Bénard, P., Garrault, S., Nonat, A., Cau-dit-Coumes, C.
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container_issue 10
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container_title Cement and concrete research
container_volume 38
creator Bénard, P.
Garrault, S.
Nonat, A.
Cau-dit-Coumes, C.
description Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosphate ions slows down the dissolution of Ca 3SiO 5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts.
doi_str_mv 10.1016/j.cemconres.2008.03.019
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subjects Adsorption
Applied sciences
Buildings. Public works
Ca 3SiO 5
Cement concrete constituents
Cements
Exact sciences and technology
Hydration
Materials
Physics
Properties of anhydrous and hydrated cement, test methods
Retardation
title Influence of orthophosphate ions on the dissolution of tricalcium silicate
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