Influence of orthophosphate ions on the dissolution of tricalcium silicate
Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosph...
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Veröffentlicht in: | Cement and concrete research 2008-10, Vol.38 (10), p.1137-1141 |
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creator | Bénard, P. Garrault, S. Nonat, A. Cau-dit-Coumes, C. |
description | Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosphate ions slows down the dissolution of Ca
3SiO
5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts. |
doi_str_mv | 10.1016/j.cemconres.2008.03.019 |
format | Article |
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3SiO
5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts.</description><identifier>ISSN: 0008-8846</identifier><identifier>EISSN: 1873-3948</identifier><identifier>DOI: 10.1016/j.cemconres.2008.03.019</identifier><identifier>CODEN: CCNRAI</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Adsorption ; Applied sciences ; Buildings. Public works ; Ca 3SiO 5 ; Cement concrete constituents ; Cements ; Exact sciences and technology ; Hydration ; Materials ; Physics ; Properties of anhydrous and hydrated cement, test methods ; Retardation</subject><ispartof>Cement and concrete research, 2008-10, Vol.38 (10), p.1137-1141</ispartof><rights>2008 Elsevier Ltd</rights><rights>2009 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c410t-cd1397f3fdfe6d848e0285ee2193269ce1b3f2079e653f3ccae8c8faed1c903</citedby><cites>FETCH-LOGICAL-c410t-cd1397f3fdfe6d848e0285ee2193269ce1b3f2079e653f3ccae8c8faed1c903</cites><orcidid>0000-0003-3704-6654</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.cemconres.2008.03.019$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=20759975$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00418730$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Bénard, P.</creatorcontrib><creatorcontrib>Garrault, S.</creatorcontrib><creatorcontrib>Nonat, A.</creatorcontrib><creatorcontrib>Cau-dit-Coumes, C.</creatorcontrib><title>Influence of orthophosphate ions on the dissolution of tricalcium silicate</title><title>Cement and concrete research</title><description>Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosphate ions slows down the dissolution of Ca
3SiO
5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts.</description><subject>Adsorption</subject><subject>Applied sciences</subject><subject>Buildings. Public works</subject><subject>Ca 3SiO 5</subject><subject>Cement concrete constituents</subject><subject>Cements</subject><subject>Exact sciences and technology</subject><subject>Hydration</subject><subject>Materials</subject><subject>Physics</subject><subject>Properties of anhydrous and hydrated cement, test methods</subject><subject>Retardation</subject><issn>0008-8846</issn><issn>1873-3948</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkE1r3DAQhkVoodukv6G-JNCDHcnyh3RcQvPFQg7pXajjEdbitTYaOdB_X5kNe81J0uiZd5iHsZ-CV4KL7nZfAR4gzBGpqjlXFZcVF_qCbYTqZSl1o76wDc8_pVJN9419J9rnZ1dLtWHPT7ObFpwBi-CKENMYjmOg42gTFj7MVIS5SCMWgycK05JybSVT9GAn8MuhID_le8Ir9tXZifDHx3nJXu9__7l7LHcvD093210JjeCphEFI3TvpBofdoBqFvFYtYi20rDsNKP5KV_NeY9dKJwEsKlDO4iBAc3nJfp1SRzuZY_QHG_-ZYL153O7MWuO8WRfn7yKzNyf2GMPbgpTMwRPgNNkZw0JGtk3TinoN7U8gxEAU0Z2TBTerZbM3Z8tmtWy4NNly7rz-GGEpC3HRzuDp3J73aLXu28xtTxxmM-8eoyHwq_bBR4RkhuA_nfUfEaiYDw</recordid><startdate>20081001</startdate><enddate>20081001</enddate><creator>Bénard, P.</creator><creator>Garrault, S.</creator><creator>Nonat, A.</creator><creator>Cau-dit-Coumes, C.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-3704-6654</orcidid></search><sort><creationdate>20081001</creationdate><title>Influence of orthophosphate ions on the dissolution of tricalcium silicate</title><author>Bénard, P. ; Garrault, S. ; Nonat, A. ; Cau-dit-Coumes, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c410t-cd1397f3fdfe6d848e0285ee2193269ce1b3f2079e653f3ccae8c8faed1c903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Adsorption</topic><topic>Applied sciences</topic><topic>Buildings. Public works</topic><topic>Ca 3SiO 5</topic><topic>Cement concrete constituents</topic><topic>Cements</topic><topic>Exact sciences and technology</topic><topic>Hydration</topic><topic>Materials</topic><topic>Physics</topic><topic>Properties of anhydrous and hydrated cement, test methods</topic><topic>Retardation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bénard, P.</creatorcontrib><creatorcontrib>Garrault, S.</creatorcontrib><creatorcontrib>Nonat, A.</creatorcontrib><creatorcontrib>Cau-dit-Coumes, C.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Cement and concrete research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bénard, P.</au><au>Garrault, S.</au><au>Nonat, A.</au><au>Cau-dit-Coumes, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of orthophosphate ions on the dissolution of tricalcium silicate</atitle><jtitle>Cement and concrete research</jtitle><date>2008-10-01</date><risdate>2008</risdate><volume>38</volume><issue>10</issue><spage>1137</spage><epage>1141</epage><pages>1137-1141</pages><issn>0008-8846</issn><eissn>1873-3948</eissn><coden>CCNRAI</coden><abstract>Tricalcium silicate dissolution in the presence of orthophosphate ions was monitored by measuring the concentrations of calcium and silicate ions in dilute suspensions using a special dissolution cell coupled to an optical emission spectrometer. Results show that increasing adsorption of orthophosphate ions slows down the dissolution of Ca
3SiO
5 and that a calcium-phosphate precipitate may form at certain orthophosphate concentrations. These observations are correlated with results of calorimetric experiments carried out during the hydration of silica-rich cement pastes in the presence of the same salts.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.cemconres.2008.03.019</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3704-6654</orcidid></addata></record> |
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subjects | Adsorption Applied sciences Buildings. Public works Ca 3SiO 5 Cement concrete constituents Cements Exact sciences and technology Hydration Materials Physics Properties of anhydrous and hydrated cement, test methods Retardation |
title | Influence of orthophosphate ions on the dissolution of tricalcium silicate |
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