Magnetic properties of Cu1+xMn2-xO4 and Ni1+xMn2-xO4 solid solutions
Magnetic properties of two spinel oxides solid solutions, Cu1+xMn2−xO4 and Ni1+xMn2−xO4, are reported. These series are characterized by two magnetic transitions: the upper one, of ferrimagnetic type, occurs at about 85 K (for copper-based) and at 105-110 K (for nickel-based spinels), independently...
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| Veröffentlicht in: | Journal of the European Ceramic Society 2007-01, Vol.27 (13-15), p.3911-3914 |
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| container_issue | 13-15 |
| container_start_page | 3911 |
| container_title | Journal of the European Ceramic Society |
| container_volume | 27 |
| creator | PEFIA, O CAILLEAUX, X PIRIOU, B DEL CANTO, M ABARCA, S RIOS, E ORTIZ, J GAUTIER, J. L LISBOA-FILHO, P. N MOURE, C |
| description | Magnetic properties of two spinel oxides solid solutions, Cu1+xMn2−xO4 and Ni1+xMn2−xO4, are reported. These series are characterized by two magnetic transitions: the upper one, of ferrimagnetic type, occurs at about 85 K (for copper-based) and at 105-110 K (for nickel-based spinels), independently of the x-content; the lower transition may be related to a Néel-type collinear ordering and takes place at 30 and 45 K, respectively. Application of moderate fields (H > 250 Oe) make both transitions to merge into one broad maximum in the magnetization, which takes place at lower temperature when applying larger fields. Magnetization cycles with temperature (ZFC/FC) or field (loops) allowed us to well characterize the ordered state. The effective moment follows the expected behavior when manganese ions are being substituted by ions of lower magnetic moment (Ni2+ and Cu2+). |
| doi_str_mv | 10.1016/j.jeurceramsoc.2007.02.058 |
| format | Article |
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The effective moment follows the expected behavior when manganese ions are being substituted by ions of lower magnetic moment (Ni2+ and Cu2+).</description><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Ceramic industries</subject><subject>Chemical industry and chemicals</subject><subject>Chemical Sciences</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Electrotechnical and electronic ceramics</subject><subject>Exact sciences and technology</subject><subject>Ferrimagnetics</subject><subject>Magnetic properties and materials</subject><subject>or physical chemistry</subject><subject>Physics</subject><subject>Studies of specific magnetic materials</subject><subject>Technical ceramics</subject><subject>Theoretical and</subject><issn>0955-2219</issn><issn>1873-619X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNpNkF9LwzAUxYMoOKffoQg-iLTepEnT69uYfyZs7kXBt5BlqaZ0bUk6md_elokOLufC4Zzz8CPkkkJCgWa3ZVLarTfW601oTMIAZAIsAZEfkRHNZRpnFN-PyQhQiJgxiqfkLIQSgEpAHJH7hf6obedM1Pqmtb5zNkRNEU239Ga3qFm8W_JI1-voxR0YoancetBt55o6nJOTQlfBXvz-MXl7fHidzuL58ul5OpnHJmWyiy1bZSmYAlGkXHKBnGccUdrC4hqNAeApgs3zlbVGSy2FBYYceZ4Li2aVjsn1fvdTV6r1bqP9t2q0U7PJXA1ev0ApQ_FF--zdPmt8E4K3xV-BghrYqVIdslMDOwVM9ez68tW-3OpgdFV4XRsX_hdyFP1B-gN3F3Gx</recordid><startdate>20070101</startdate><enddate>20070101</enddate><creator>PEFIA, O</creator><creator>CAILLEAUX, X</creator><creator>PIRIOU, B</creator><creator>DEL CANTO, M</creator><creator>ABARCA, S</creator><creator>RIOS, E</creator><creator>ORTIZ, J</creator><creator>GAUTIER, J. 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N</au><au>MOURE, C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Magnetic properties of Cu1+xMn2-xO4 and Ni1+xMn2-xO4 solid solutions</atitle><jtitle>Journal of the European Ceramic Society</jtitle><date>2007-01-01</date><risdate>2007</risdate><volume>27</volume><issue>13-15</issue><spage>3911</spage><epage>3914</epage><pages>3911-3914</pages><issn>0955-2219</issn><eissn>1873-619X</eissn><abstract>Magnetic properties of two spinel oxides solid solutions, Cu1+xMn2−xO4 and Ni1+xMn2−xO4, are reported. These series are characterized by two magnetic transitions: the upper one, of ferrimagnetic type, occurs at about 85 K (for copper-based) and at 105-110 K (for nickel-based spinels), independently of the x-content; the lower transition may be related to a Néel-type collinear ordering and takes place at 30 and 45 K, respectively. Application of moderate fields (H > 250 Oe) make both transitions to merge into one broad maximum in the magnetization, which takes place at lower temperature when applying larger fields. Magnetization cycles with temperature (ZFC/FC) or field (loops) allowed us to well characterize the ordered state. The effective moment follows the expected behavior when manganese ions are being substituted by ions of lower magnetic moment (Ni2+ and Cu2+).</abstract><cop>Oxford</cop><pub>Elsevier</pub><doi>10.1016/j.jeurceramsoc.2007.02.058</doi><tpages>4</tpages></addata></record> |
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| source | Elsevier ScienceDirect Journals |
| subjects | Applied sciences Building materials. Ceramics. Glasses Ceramic industries Chemical industry and chemicals Chemical Sciences Condensed matter: electronic structure, electrical, magnetic, and optical properties Electrotechnical and electronic ceramics Exact sciences and technology Ferrimagnetics Magnetic properties and materials or physical chemistry Physics Studies of specific magnetic materials Technical ceramics Theoretical and |
| title | Magnetic properties of Cu1+xMn2-xO4 and Ni1+xMn2-xO4 solid solutions |
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