Renewable materials as precursors of linear nitrile-acid derivatives via cross-metathesis of fatty esters and acids with acrylonitrile and fumaronitrile

Renewable materials as precursors of linear nitrile-acid derivatives via cross-metathesis of fatty esters and acids with acrylonitrile and fumaronitrile

The cross-metathesis of fatty acids and esters, as renewable raw materials, with acrylonitrile and fumaronitrile is presented. The cross-metathesis reactions of both terminal and internal double bond containing compounds were performed using a ruthenium catalyst and led to bifunctional nitrile-ester...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2009-01, Vol.11 (2), p.152-155
Hauptverfasser: Malacea, Raluca, Fischmeister, Cedric, Bruneau, Christian, Dubois, Jean-Luc, Couturier, Jean-Luc, Dixneuf, Pierre H
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Catalysis
Chemical Sciences
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container_title Green chemistry : an international journal and green chemistry resource : GC
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creator Malacea, Raluca
Fischmeister, Cedric
Bruneau, Christian
Dubois, Jean-Luc
Couturier, Jean-Luc
Dixneuf, Pierre H
description The cross-metathesis of fatty acids and esters, as renewable raw materials, with acrylonitrile and fumaronitrile is presented. The cross-metathesis reactions of both terminal and internal double bond containing compounds were performed using a ruthenium catalyst and led to bifunctional nitrile-esters or nitrile-acids with high conversions. The tandem ruthenium catalysed cross-metathesis and hydrogenation provide precursors of aminoacid monomers for the production of polyamides from renewable resources.
doi_str_mv 10.1039/B816917A
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subjects Catalysis
Chemical Sciences
title Renewable materials as precursors of linear nitrile-acid derivatives via cross-metathesis of fatty esters and acids with acrylonitrile and fumaronitrile
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