Solid−Liquid Equilibria under High Pressure of Nine Pure n-Alkylbenzenes

Solid−Liquid Equilibria under High Pressure of Nine Pure n-Alkylbenzenes

The melting temperatures of nine n-alkylbenzenes (undecylbenzene, dodecylbenzene, tridecylbenzene, tetradecylbenzene, pentadecylbenzene, hexadecylbenzene, heptadecylbenzene, octadecylbenzene, and nonadecylbenzene) were measured by means of a high-pressure microscope up to 100 MPa. The experimental d...

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Veröffentlicht in:Journal of chemical and engineering data 2008-01, Vol.53 (1), p.233-237
Hauptverfasser: Milhet, Michel, Pauly, Jérôme, Coutinho, João A.P, Daridon, Jean-Luc
Format: Artikel
Sprache:eng
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Chemical Physics
Condensed matter: structure, mechanical and thermal properties
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Physics
Solid-liquid transitions
Specific phase transitions
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container_issue 1
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container_title Journal of chemical and engineering data
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creator Milhet, Michel
Pauly, Jérôme
Coutinho, João A.P
Daridon, Jean-Luc
description The melting temperatures of nine n-alkylbenzenes (undecylbenzene, dodecylbenzene, tridecylbenzene, tetradecylbenzene, pentadecylbenzene, hexadecylbenzene, heptadecylbenzene, octadecylbenzene, and nonadecylbenzene) were measured by means of a high-pressure microscope up to 100 MPa. The experimental device used in this work allowed the distinction between stable and metastable solid phases. The influences of the alkyl chain length and pressure on the melting temperatures of the stable solid phases are discussed.
doi_str_mv 10.1021/je700529y
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subjects Chemical Physics
Condensed matter: structure, mechanical and thermal properties
Equations of state, phase equilibria, and phase transitions
Exact sciences and technology
Physics
Solid-liquid transitions
Specific phase transitions
title Solid−Liquid Equilibria under High Pressure of Nine Pure n-Alkylbenzenes
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