Conformational analysis of galactomannans: from oligomeric segments to polymeric chains

Conformational features of the glycosidic bond linking two mannosyl units of four different oligomeric fragments of galactomannans have been calculated by means of adiabatic mapping of the glycosidic Φ, Ψ torsion angles using the MM3 force field. These fragments differed in their substitution patter...

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Veröffentlicht in:	Carbohydrate polymers 1998, Vol.37 (1), p.25-39
Hauptverfasser:	Petkowicz, C.L.O., Reicher, F., Mazeau, K.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences chemical structure energy minimalization Exact sciences and technology Galactomannans glycosidic linkages molecular conformation Monte Carlo method Natural polymers Oligomeric segments Physicochemistry of polymers Polymeric chains polymers potential energy Starch and polysaccharides
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