Synthesis of polyurethane/polyethylene grafted polymers using cyclotriphosphazene as a coupling agent
The reaction between a dihydroxyphenoxycyclotriphosphazene containing allylic functions, 3, and hexamethylene‐1,6‐diisocyanate (HDI) leads to a new cyclotriphosphazene‐substituted polyurethane 4. The structures of both classes of compounds involved in that synthesis were investigated by 31P‐, 13C‐,...
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| Veröffentlicht in: | Journal of applied polymer science 2003-08, Vol.89 (7), p.1925-1934 |
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| container_end_page | 1934 |
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| container_issue | 7 |
| container_start_page | 1925 |
| container_title | Journal of applied polymer science |
| container_volume | 89 |
| creator | Dez, Isabelle De Jaeger, Roger |
| description | The reaction between a dihydroxyphenoxycyclotriphosphazene containing allylic functions, 3, and hexamethylene‐1,6‐diisocyanate (HDI) leads to a new cyclotriphosphazene‐substituted polyurethane 4. The structures of both classes of compounds involved in that synthesis were investigated by 31P‐, 13C‐, and 1H‐NMR, infrared, and mass spectrometries, size‐exclusion chromatography, and elemental analysis. The thermal behavior of 4 was investigated and compared to that of hexaphenoxycyclotriphosphazene, N3P3(OC6H5)6, and of a polyurethane synthesized from 1,3‐bis(hydroxy)benzene and HDI. The free‐radical‐promoted grafting of 4 onto the polyethylene surface is described. The resultant surface was studied by ATR–IR, XPS, and contact‐angle techniques. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1925–1934, 2003 |
| doi_str_mv | 10.1002/app.12374 |
| format | Article |
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The structures of both classes of compounds involved in that synthesis were investigated by 31P‐, 13C‐, and 1H‐NMR, infrared, and mass spectrometries, size‐exclusion chromatography, and elemental analysis. The thermal behavior of 4 was investigated and compared to that of hexaphenoxycyclotriphosphazene, N3P3(OC6H5)6, and of a polyurethane synthesized from 1,3‐bis(hydroxy)benzene and HDI. The free‐radical‐promoted grafting of 4 onto the polyethylene surface is described. The resultant surface was studied by ATR–IR, XPS, and contact‐angle techniques. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1925–1934, 2003</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.12374</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polycondensation ; polyethylene (PE) ; polyurethanes ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; surfaces ; thermal properties</subject><ispartof>Journal of applied polymer science, 2003-08, Vol.89 (7), p.1925-1934</ispartof><rights>Copyright © 2003 Wiley Periodicals, Inc.</rights><rights>2003 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4004-e2768bac3be5b6cc6559f3166dd67d6722dffeff6ebbf64c2f6b9ef4d08eba63</citedby><cites>FETCH-LOGICAL-c4004-e2768bac3be5b6cc6559f3166dd67d6722dffeff6ebbf64c2f6b9ef4d08eba63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.12374$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.12374$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14850108$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00274899$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Dez, Isabelle</creatorcontrib><creatorcontrib>De Jaeger, Roger</creatorcontrib><title>Synthesis of polyurethane/polyethylene grafted polymers using cyclotriphosphazene as a coupling agent</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The reaction between a dihydroxyphenoxycyclotriphosphazene containing allylic functions, 3, and hexamethylene‐1,6‐diisocyanate (HDI) leads to a new cyclotriphosphazene‐substituted polyurethane 4. The structures of both classes of compounds involved in that synthesis were investigated by 31P‐, 13C‐, and 1H‐NMR, infrared, and mass spectrometries, size‐exclusion chromatography, and elemental analysis. The thermal behavior of 4 was investigated and compared to that of hexaphenoxycyclotriphosphazene, N3P3(OC6H5)6, and of a polyurethane synthesized from 1,3‐bis(hydroxy)benzene and HDI. The free‐radical‐promoted grafting of 4 onto the polyethylene surface is described. The resultant surface was studied by ATR–IR, XPS, and contact‐angle techniques. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1925–1934, 2003</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polycondensation</subject><subject>polyethylene (PE)</subject><subject>polyurethanes</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>surfaces</subject><subject>thermal properties</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNp1kM1u3CAURlHUSp2mWfQNvEmlLpwBjLG9HI2av47aVI2SJcL4MqZljAN2WufpgzNpsqqEBBfOdyQ-hD4SfEIwpkvZ9yeEZgU7QAuCqyJlnJZv0CK-kbSsqvwdeh_CL4wJyTFfIPg5dUMLwYTE6aR3dho9DK3sYDkP8ThZ6CDZeqkHaJ6IHfiQjMF020RNyrrBm751oW_lw4zKkMhEubG3MyG30A0f0FstbYCj5_0QXZ9-uV6fp5vvZxfr1SZVDGOWAi14WUuV1ZDXXCme55XOCOdNw4u4KG20Bq051LXmTFHN6wo0a3AJteTZIfq817bSit6bnfSTcNKI89VGzHexhYLFFu5JZD_t2d67uxHCIHYmKLA2ft2NQdAS05Kz6lWqvAvBg34xEyzmzkXsXDx1HtnjZ6kMSlrtZadMeA2wMscEl5Fb7rk_xsL0f6FYXV39M6f7hAkD_H1JSP9b8CIrcnH77UxkZP01_3F5I26zR9HjolQ</recordid><startdate>20030815</startdate><enddate>20030815</enddate><creator>Dez, Isabelle</creator><creator>De Jaeger, Roger</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope></search><sort><creationdate>20030815</creationdate><title>Synthesis of polyurethane/polyethylene grafted polymers using cyclotriphosphazene as a coupling agent</title><author>Dez, Isabelle ; De Jaeger, Roger</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4004-e2768bac3be5b6cc6559f3166dd67d6722dffeff6ebbf64c2f6b9ef4d08eba63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polycondensation</topic><topic>polyethylene (PE)</topic><topic>polyurethanes</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>surfaces</topic><topic>thermal properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dez, Isabelle</creatorcontrib><creatorcontrib>De Jaeger, Roger</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dez, Isabelle</au><au>De Jaeger, Roger</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of polyurethane/polyethylene grafted polymers using cyclotriphosphazene as a coupling agent</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2003-08-15</date><risdate>2003</risdate><volume>89</volume><issue>7</issue><spage>1925</spage><epage>1934</epage><pages>1925-1934</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The reaction between a dihydroxyphenoxycyclotriphosphazene containing allylic functions, 3, and hexamethylene‐1,6‐diisocyanate (HDI) leads to a new cyclotriphosphazene‐substituted polyurethane 4. The structures of both classes of compounds involved in that synthesis were investigated by 31P‐, 13C‐, and 1H‐NMR, infrared, and mass spectrometries, size‐exclusion chromatography, and elemental analysis. The thermal behavior of 4 was investigated and compared to that of hexaphenoxycyclotriphosphazene, N3P3(OC6H5)6, and of a polyurethane synthesized from 1,3‐bis(hydroxy)benzene and HDI. The free‐radical‐promoted grafting of 4 onto the polyethylene surface is described. The resultant surface was studied by ATR–IR, XPS, and contact‐angle techniques. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1925–1934, 2003</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.12374</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of applied polymer science, 2003-08, Vol.89 (7), p.1925-1934 |
| issn | 0021-8995 1097-4628 |
| language | eng |
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| source | Wiley Journals |
| subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polycondensation polyethylene (PE) polyurethanes Preparation, kinetics, thermodynamics, mechanism and catalysts surfaces thermal properties |
| title | Synthesis of polyurethane/polyethylene grafted polymers using cyclotriphosphazene as a coupling agent |
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