Infrared Spectroelectrochemical Studies of Divided Carbon Electrodes in Acetonitrile-Sodium Tetrafluoroborate Solutions

Infrared Spectroelectrochemical Studies of Divided Carbon Electrodes in Acetonitrile-Sodium Tetrafluoroborate Solutions

Fourier transform infrared spectroelectrochemistry has been used to study the vibrational spectrum of a thin layer of the organic electrolyte in contact with a divided carbon supercapacitor electrode. Variations in the absorption of peaks characteristic of the solvent and of the support electrolyte...

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Veröffentlicht in:Journal of the Electrochemical Society 2005, Vol.152 (2), p.A411-A414
Hauptverfasser: De Backer, Marc, Berrier, Elise, Martinon, Yann, Dujardin, Nicolas, Dufour, Florence, Peres, Jean Paul, Jehoulet, Christophe
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Engineering Sciences
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container_end_page A414
container_issue 2
container_start_page A411
container_title Journal of the Electrochemical Society
container_volume 152
creator De Backer, Marc
Berrier, Elise
Martinon, Yann
Dujardin, Nicolas
Dufour, Florence
Peres, Jean Paul
Jehoulet, Christophe
description Fourier transform infrared spectroelectrochemistry has been used to study the vibrational spectrum of a thin layer of the organic electrolyte in contact with a divided carbon supercapacitor electrode. Variations in the absorption of peaks characteristic of the solvent and of the support electrolyte during an anodic potential scan have been observed. The presence of adsorbed water was detected. The formation of a stable adduct of CH3CN and BF3 under anodic potential was identified.
doi_str_mv 10.1149/1.1851031
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Engineering Sciences
title Infrared Spectroelectrochemical Studies of Divided Carbon Electrodes in Acetonitrile-Sodium Tetrafluoroborate Solutions
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