Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers
The dynamical properties of semidilute solutions of supramolecular polymers formed from molecular recognition directed association between monomers bearing complementary hydrogen bonding groups were investigated by rheological and dynamic light scattering experiments. The steady-state flow curves sh...
Gespeichert in:
| Veröffentlicht in: | Physical review. E, Statistical, nonlinear, and soft matter physics Statistical, nonlinear, and soft matter physics, 2007-12, Vol.76 (6 Pt 1), p.061804-061804, Article 061804 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 061804 |
|---|---|
| container_issue | 6 Pt 1 |
| container_start_page | 061804 |
| container_title | Physical review. E, Statistical, nonlinear, and soft matter physics |
| container_volume | 76 |
| creator | Buhler, Eric Candau, Sauveur-Jean Kolomiets, Elena Lehn, Jean-Marie |
| description | The dynamical properties of semidilute solutions of supramolecular polymers formed from molecular recognition directed association between monomers bearing complementary hydrogen bonding groups were investigated by rheological and dynamic light scattering experiments. The steady-state flow curves showed a shear banding type instability, namely the occurrence of a stress plateau sigma(p) above a critical shear rate .gamma(c) . The values of sigma(p)and .gamma(c) were found to be of the same order of magnitude as those of the elastic plateau modulus and the inverse stress relaxation time, respectively. The above features are in agreement with the theoretical predictions based on the reptation model. Dynamic light scattering experiments showed the presence in the autocorrelation function of the concentration fluctuations of a slow viscoelastic relaxation process that is likely to be of Rouse type. |
| doi_str_mv | 10.1103/physreve.76.061804 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_00202866v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>70068209</sourcerecordid><originalsourceid>FETCH-LOGICAL-c401t-648617227d345b19bfeb6c2e5a1771cba25431c5b377790f714e63b1cf503c193</originalsourceid><addsrcrecordid>eNpFkE9r3DAQxUVISNI0X6CH4lMgB29mJEvyHkP-NIGFhJCSo5DlcddFtlxpveBvH293aU9veLz3YH6MfUNYIIK4GdZTirSlhVYLUFhCccTOUUrIudDqeHeLZS60lGfsS0q_AQQXZXHKzrDkQpSKn7OP-6m3Xeusz4YYBoqbllIWmixR19atHzeUpTBLG_q__nqqY_hFfV6FvqY6S-MQbRc8udHbmA3BTx3F9JWdNNYnujzoBfv5-PB-95SvXn48392uclcAbnJVlAo157oWhaxwWTVUKcdJWtQaXWW5LAQ6WQmt9RIajQUpUaFrJAiHS3HBrve7a-vNENvOxskE25qn25XZeQAceKnUFufs1T47f_pnpLQxXZsceW97CmMyGkCVHHajfB90MaQZcfNvGcHs0JvXGf0bbR-MVmaPfi59P6yPVUf1_8qBtfgEjMaBzA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>70068209</pqid></control><display><type>article</type><title>Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers</title><source>American Physical Society Journals</source><creator>Buhler, Eric ; Candau, Sauveur-Jean ; Kolomiets, Elena ; Lehn, Jean-Marie</creator><creatorcontrib>Buhler, Eric ; Candau, Sauveur-Jean ; Kolomiets, Elena ; Lehn, Jean-Marie</creatorcontrib><description>The dynamical properties of semidilute solutions of supramolecular polymers formed from molecular recognition directed association between monomers bearing complementary hydrogen bonding groups were investigated by rheological and dynamic light scattering experiments. The steady-state flow curves showed a shear banding type instability, namely the occurrence of a stress plateau sigma(p) above a critical shear rate .gamma(c) . The values of sigma(p)and .gamma(c) were found to be of the same order of magnitude as those of the elastic plateau modulus and the inverse stress relaxation time, respectively. The above features are in agreement with the theoretical predictions based on the reptation model. Dynamic light scattering experiments showed the presence in the autocorrelation function of the concentration fluctuations of a slow viscoelastic relaxation process that is likely to be of Rouse type.</description><identifier>ISSN: 1539-3755</identifier><identifier>EISSN: 1550-2376</identifier><identifier>DOI: 10.1103/physreve.76.061804</identifier><identifier>PMID: 18233862</identifier><language>eng</language><publisher>United States: American Physical Society</publisher><subject>Biomechanics ; Engineering Sciences ; Mechanics ; Physics</subject><ispartof>Physical review. E, Statistical, nonlinear, and soft matter physics, 2007-12, Vol.76 (6 Pt 1), p.061804-061804, Article 061804</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c401t-648617227d345b19bfeb6c2e5a1771cba25431c5b377790f714e63b1cf503c193</citedby><cites>FETCH-LOGICAL-c401t-648617227d345b19bfeb6c2e5a1771cba25431c5b377790f714e63b1cf503c193</cites><orcidid>0000-0001-8981-4593 ; 0000-0003-3946-1982</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,777,781,882,2863,2864,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18233862$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00202866$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Buhler, Eric</creatorcontrib><creatorcontrib>Candau, Sauveur-Jean</creatorcontrib><creatorcontrib>Kolomiets, Elena</creatorcontrib><creatorcontrib>Lehn, Jean-Marie</creatorcontrib><title>Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers</title><title>Physical review. E, Statistical, nonlinear, and soft matter physics</title><addtitle>Phys Rev E Stat Nonlin Soft Matter Phys</addtitle><description>The dynamical properties of semidilute solutions of supramolecular polymers formed from molecular recognition directed association between monomers bearing complementary hydrogen bonding groups were investigated by rheological and dynamic light scattering experiments. The steady-state flow curves showed a shear banding type instability, namely the occurrence of a stress plateau sigma(p) above a critical shear rate .gamma(c) . The values of sigma(p)and .gamma(c) were found to be of the same order of magnitude as those of the elastic plateau modulus and the inverse stress relaxation time, respectively. The above features are in agreement with the theoretical predictions based on the reptation model. Dynamic light scattering experiments showed the presence in the autocorrelation function of the concentration fluctuations of a slow viscoelastic relaxation process that is likely to be of Rouse type.</description><subject>Biomechanics</subject><subject>Engineering Sciences</subject><subject>Mechanics</subject><subject>Physics</subject><issn>1539-3755</issn><issn>1550-2376</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNpFkE9r3DAQxUVISNI0X6CH4lMgB29mJEvyHkP-NIGFhJCSo5DlcddFtlxpveBvH293aU9veLz3YH6MfUNYIIK4GdZTirSlhVYLUFhCccTOUUrIudDqeHeLZS60lGfsS0q_AQQXZXHKzrDkQpSKn7OP-6m3Xeusz4YYBoqbllIWmixR19atHzeUpTBLG_q__nqqY_hFfV6FvqY6S-MQbRc8udHbmA3BTx3F9JWdNNYnujzoBfv5-PB-95SvXn48392uclcAbnJVlAo157oWhaxwWTVUKcdJWtQaXWW5LAQ6WQmt9RIajQUpUaFrJAiHS3HBrve7a-vNENvOxskE25qn25XZeQAceKnUFufs1T47f_pnpLQxXZsceW97CmMyGkCVHHajfB90MaQZcfNvGcHs0JvXGf0bbR-MVmaPfi59P6yPVUf1_8qBtfgEjMaBzA</recordid><startdate>20071201</startdate><enddate>20071201</enddate><creator>Buhler, Eric</creator><creator>Candau, Sauveur-Jean</creator><creator>Kolomiets, Elena</creator><creator>Lehn, Jean-Marie</creator><general>American Physical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-8981-4593</orcidid><orcidid>https://orcid.org/0000-0003-3946-1982</orcidid></search><sort><creationdate>20071201</creationdate><title>Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers</title><author>Buhler, Eric ; Candau, Sauveur-Jean ; Kolomiets, Elena ; Lehn, Jean-Marie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c401t-648617227d345b19bfeb6c2e5a1771cba25431c5b377790f714e63b1cf503c193</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Biomechanics</topic><topic>Engineering Sciences</topic><topic>Mechanics</topic><topic>Physics</topic><toplevel>online_resources</toplevel><creatorcontrib>Buhler, Eric</creatorcontrib><creatorcontrib>Candau, Sauveur-Jean</creatorcontrib><creatorcontrib>Kolomiets, Elena</creatorcontrib><creatorcontrib>Lehn, Jean-Marie</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Physical review. E, Statistical, nonlinear, and soft matter physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Buhler, Eric</au><au>Candau, Sauveur-Jean</au><au>Kolomiets, Elena</au><au>Lehn, Jean-Marie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers</atitle><jtitle>Physical review. E, Statistical, nonlinear, and soft matter physics</jtitle><addtitle>Phys Rev E Stat Nonlin Soft Matter Phys</addtitle><date>2007-12-01</date><risdate>2007</risdate><volume>76</volume><issue>6 Pt 1</issue><spage>061804</spage><epage>061804</epage><pages>061804-061804</pages><artnum>061804</artnum><issn>1539-3755</issn><eissn>1550-2376</eissn><abstract>The dynamical properties of semidilute solutions of supramolecular polymers formed from molecular recognition directed association between monomers bearing complementary hydrogen bonding groups were investigated by rheological and dynamic light scattering experiments. The steady-state flow curves showed a shear banding type instability, namely the occurrence of a stress plateau sigma(p) above a critical shear rate .gamma(c) . The values of sigma(p)and .gamma(c) were found to be of the same order of magnitude as those of the elastic plateau modulus and the inverse stress relaxation time, respectively. The above features are in agreement with the theoretical predictions based on the reptation model. Dynamic light scattering experiments showed the presence in the autocorrelation function of the concentration fluctuations of a slow viscoelastic relaxation process that is likely to be of Rouse type.</abstract><cop>United States</cop><pub>American Physical Society</pub><pmid>18233862</pmid><doi>10.1103/physreve.76.061804</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0001-8981-4593</orcidid><orcidid>https://orcid.org/0000-0003-3946-1982</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1539-3755 |
| ispartof | Physical review. E, Statistical, nonlinear, and soft matter physics, 2007-12, Vol.76 (6 Pt 1), p.061804-061804, Article 061804 |
| issn | 1539-3755 1550-2376 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00202866v1 |
| source | American Physical Society Journals |
| subjects | Biomechanics Engineering Sciences Mechanics Physics |
| title | Dynamical properties of semidilute solutions of hydrogen-bonded supramolecular polymers |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T07%3A13%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dynamical%20properties%20of%20semidilute%20solutions%20of%20hydrogen-bonded%20supramolecular%20polymers&rft.jtitle=Physical%20review.%20E,%20Statistical,%20nonlinear,%20and%20soft%20matter%20physics&rft.au=Buhler,%20Eric&rft.date=2007-12-01&rft.volume=76&rft.issue=6%20Pt%201&rft.spage=061804&rft.epage=061804&rft.pages=061804-061804&rft.artnum=061804&rft.issn=1539-3755&rft.eissn=1550-2376&rft_id=info:doi/10.1103/physreve.76.061804&rft_dat=%3Cproquest_hal_p%3E70068209%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=70068209&rft_id=info:pmid/18233862&rfr_iscdi=true |