Structure of Synthetic K-rich Birnessites Obtained by HighTemperature Decomposition of KMnO4. 2 Phase and Structural Heterogeneities

Synthetic K-rich birnessites (KBi) were prepared from the thermal decomposition of a fine-grained KMnO4 powder heated in air atmosphere at temperatures ranging from 2001000°C. The qualitative analysis of powder X-ray diffraction (XRD) patterns reveals a complex range of structural transformations fr...

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Veröffentlicht in:Chemistry of materials 2004, Vol.16, p.1890-1905
Hauptverfasser: Gaillot, Anne-Claire, Drits, Victor.A., Plançon, Alain, Lanson, Bruno
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Sprache:eng
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