A molecular and isotopic study of the organic matter from the Paris Basin, France
Thirteen Liassic sedimentary rocks of increasing depth and three petroleums from the Paris Basin were studied for 13C 12C isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of n-alkan...
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| Veröffentlicht in: | Geochimica et cosmochimica acta 1994, Vol.58 (1), p.209-221 |
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| creator | Lichtfouse, Eric Albrecht, Pierre Béhar, Françoise Hayes, John M |
| description | Thirteen Liassic sedimentary rocks of increasing depth and three petroleums from the Paris Basin were studied for
13C
12C
isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of
n-alkanes from mature sedimentary rocks and petroleums fall in a narrow range (2%.), except for the deepest Hettangian rock and the Trias petroleum, for which the short-chain
n-alkanes are enriched and depleted in
13C, respectively. Most of the molecular parameters increase over the 2000–2500 m depth range, reflecting the transformation of the organic matter at the onset of petroleum generation. In this zone, carbonate content and carbon isotopic composition of carbonates, as well as molecular parameters, are distinct for the Toarcian and Hettangian source rocks and suggest a migration of organic matter from these two formations. Two novel molecular parameters were defined for this task: one using methyltriaromatic steroids from organic extracts; the other using 1-methylphenanthrene and 2-methylanthracene from kerogen pyrolysates. The anomalous high maturity of the Dogger petroleum relative to the maturitydepth trend of the source rocks is used to estimate the minimal vertical distance of migration of the organic matter from the source rock to the reservoir. |
| doi_str_mv | 10.1016/0016-7037(94)90458-8 |
| format | Article |
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13C
12C
isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of
n-alkanes from mature sedimentary rocks and petroleums fall in a narrow range (2%.), except for the deepest Hettangian rock and the Trias petroleum, for which the short-chain
n-alkanes are enriched and depleted in
13C, respectively. Most of the molecular parameters increase over the 2000–2500 m depth range, reflecting the transformation of the organic matter at the onset of petroleum generation. In this zone, carbonate content and carbon isotopic composition of carbonates, as well as molecular parameters, are distinct for the Toarcian and Hettangian source rocks and suggest a migration of organic matter from these two formations. Two novel molecular parameters were defined for this task: one using methyltriaromatic steroids from organic extracts; the other using 1-methylphenanthrene and 2-methylanthracene from kerogen pyrolysates. The anomalous high maturity of the Dogger petroleum relative to the maturitydepth trend of the source rocks is used to estimate the minimal vertical distance of migration of the organic matter from the source rock to the reservoir.</description><identifier>ISSN: 0016-7037</identifier><identifier>EISSN: 1872-9533</identifier><identifier>DOI: 10.1016/0016-7037(94)90458-8</identifier><identifier>PMID: 11540247</identifier><language>eng</language><publisher>Legacy CDMS: Elsevier Ltd</publisher><subject>Alkanes - analysis ; Alkanes - chemistry ; Analytical chemistry ; Anthracenes - analysis ; Anthracenes - chemistry ; Calcium Carbonate - analysis ; Calcium Carbonate - chemistry ; Carbon - analysis ; Carbon - chemistry ; Carbon Isotopes ; Carbonates - analysis ; Carbonates - chemistry ; Chemical Sciences ; domain_sde.mcg.cpe ; Earth Sciences ; Environmental Sciences ; Exobiology ; Fossils ; France ; Gas Chromatography-Mass Spectrometry ; Geochemistry ; Geologic Sediments - analysis ; Geologic Sediments - chemistry ; Geophysics ; Global Changes ; Paleontology ; Petroleum - analysis ; Phenanthrenes - analysis ; Phenanthrenes - chemistry ; Sciences of the Universe ; Space life sciences ; Stereoisomerism ; Steroids - analysis ; Steroids - chemistry</subject><ispartof>Geochimica et cosmochimica acta, 1994, Vol.58 (1), p.209-221</ispartof><rights>1994</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a513t-69fd356917b4fbf9f5f6c7ced449337aa4bcc3004bb90f813c484ea4f377ef513</citedby><cites>FETCH-LOGICAL-a513t-69fd356917b4fbf9f5f6c7ced449337aa4bcc3004bb90f813c484ea4f377ef513</cites><orcidid>0000-0002-8535-8073</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/0016703794904588$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/11540247$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00191892$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Lichtfouse, Eric</creatorcontrib><creatorcontrib>Albrecht, Pierre</creatorcontrib><creatorcontrib>Béhar, Françoise</creatorcontrib><creatorcontrib>Hayes, John M</creatorcontrib><title>A molecular and isotopic study of the organic matter from the Paris Basin, France</title><title>Geochimica et cosmochimica acta</title><addtitle>Geochim Cosmochim Acta</addtitle><description>Thirteen Liassic sedimentary rocks of increasing depth and three petroleums from the Paris Basin were studied for
13C
12C
isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of
n-alkanes from mature sedimentary rocks and petroleums fall in a narrow range (2%.), except for the deepest Hettangian rock and the Trias petroleum, for which the short-chain
n-alkanes are enriched and depleted in
13C, respectively. Most of the molecular parameters increase over the 2000–2500 m depth range, reflecting the transformation of the organic matter at the onset of petroleum generation. In this zone, carbonate content and carbon isotopic composition of carbonates, as well as molecular parameters, are distinct for the Toarcian and Hettangian source rocks and suggest a migration of organic matter from these two formations. Two novel molecular parameters were defined for this task: one using methyltriaromatic steroids from organic extracts; the other using 1-methylphenanthrene and 2-methylanthracene from kerogen pyrolysates. The anomalous high maturity of the Dogger petroleum relative to the maturitydepth trend of the source rocks is used to estimate the minimal vertical distance of migration of the organic matter from the source rock to the reservoir.</description><subject>Alkanes - analysis</subject><subject>Alkanes - chemistry</subject><subject>Analytical chemistry</subject><subject>Anthracenes - analysis</subject><subject>Anthracenes - chemistry</subject><subject>Calcium Carbonate - analysis</subject><subject>Calcium Carbonate - chemistry</subject><subject>Carbon - analysis</subject><subject>Carbon - chemistry</subject><subject>Carbon Isotopes</subject><subject>Carbonates - analysis</subject><subject>Carbonates - chemistry</subject><subject>Chemical Sciences</subject><subject>domain_sde.mcg.cpe</subject><subject>Earth Sciences</subject><subject>Environmental Sciences</subject><subject>Exobiology</subject><subject>Fossils</subject><subject>France</subject><subject>Gas Chromatography-Mass Spectrometry</subject><subject>Geochemistry</subject><subject>Geologic Sediments - analysis</subject><subject>Geologic Sediments - chemistry</subject><subject>Geophysics</subject><subject>Global Changes</subject><subject>Paleontology</subject><subject>Petroleum - analysis</subject><subject>Phenanthrenes - analysis</subject><subject>Phenanthrenes - chemistry</subject><subject>Sciences of the Universe</subject><subject>Space life sciences</subject><subject>Stereoisomerism</subject><subject>Steroids - analysis</subject><subject>Steroids - chemistry</subject><issn>0016-7037</issn><issn>1872-9533</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><sourceid>CYI</sourceid><sourceid>EIF</sourceid><recordid>eNqFkdFqFTEQhoMo9rT6BkVyJRbcmmySTXIjHEtrhQNV0Oswm01sZHdzTHYLfXuz3UO9a28SmPnmn5l_EDql5JwS2nwi5akkYfKD5meacKEq9QJtqJJ1pQVjL9HmETlCxzn_IYRIIchrdESp4KTmcoN-bPEQe2fnHhKGscMhxynug8V5mrt7HD2ebh2O6TeMJTjANLmEfYrDQ_w7pJDxF8hh_IivEozWvUGvPPTZvT38J-jX1eXPi-tqd_P128V2V4GgbKoa7TsmGk1ly33rtRe-sdK6jnPNmATgrbWMEN62mnhFmeWKO-CeSel8kThBZ6vuLfRmn8IA6d5ECOZ6uzNLrGyvqdL13cK-X9l9in9nlyczhGxd38Po4pyNlJTWqvR9DqSNlqJRiyJfQZtizsn5xxEoMct9lvaNWcw3mpuH-xhVyt4d9Od2cN3_osNBCnC6AiNkMOOUsqmLCYQozYUo6c9r2hVn74JLJtvgiutdSM5Opovh6QH-AabspY4</recordid><startdate>1994</startdate><enddate>1994</enddate><creator>Lichtfouse, Eric</creator><creator>Albrecht, Pierre</creator><creator>Béhar, Françoise</creator><creator>Hayes, John M</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>CYE</scope><scope>CYI</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-8535-8073</orcidid></search><sort><creationdate>1994</creationdate><title>A molecular and isotopic study of the organic matter from the Paris Basin, France</title><author>Lichtfouse, Eric ; Albrecht, Pierre ; Béhar, Françoise ; Hayes, John M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a513t-69fd356917b4fbf9f5f6c7ced449337aa4bcc3004bb90f813c484ea4f377ef513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Alkanes - analysis</topic><topic>Alkanes - chemistry</topic><topic>Analytical chemistry</topic><topic>Anthracenes - analysis</topic><topic>Anthracenes - chemistry</topic><topic>Calcium Carbonate - analysis</topic><topic>Calcium Carbonate - chemistry</topic><topic>Carbon - analysis</topic><topic>Carbon - chemistry</topic><topic>Carbon Isotopes</topic><topic>Carbonates - analysis</topic><topic>Carbonates - chemistry</topic><topic>Chemical Sciences</topic><topic>domain_sde.mcg.cpe</topic><topic>Earth Sciences</topic><topic>Environmental Sciences</topic><topic>Exobiology</topic><topic>Fossils</topic><topic>France</topic><topic>Gas Chromatography-Mass Spectrometry</topic><topic>Geochemistry</topic><topic>Geologic Sediments - analysis</topic><topic>Geologic Sediments - chemistry</topic><topic>Geophysics</topic><topic>Global Changes</topic><topic>Paleontology</topic><topic>Petroleum - analysis</topic><topic>Phenanthrenes - analysis</topic><topic>Phenanthrenes - chemistry</topic><topic>Sciences of the Universe</topic><topic>Space life sciences</topic><topic>Stereoisomerism</topic><topic>Steroids - analysis</topic><topic>Steroids - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lichtfouse, Eric</creatorcontrib><creatorcontrib>Albrecht, Pierre</creatorcontrib><creatorcontrib>Béhar, Françoise</creatorcontrib><creatorcontrib>Hayes, John M</creatorcontrib><collection>NASA Scientific and Technical Information</collection><collection>NASA Technical Reports Server</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Geochimica et cosmochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lichtfouse, Eric</au><au>Albrecht, Pierre</au><au>Béhar, Françoise</au><au>Hayes, John M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A molecular and isotopic study of the organic matter from the Paris Basin, France</atitle><jtitle>Geochimica et cosmochimica acta</jtitle><addtitle>Geochim Cosmochim Acta</addtitle><date>1994</date><risdate>1994</risdate><volume>58</volume><issue>1</issue><spage>209</spage><epage>221</epage><pages>209-221</pages><issn>0016-7037</issn><eissn>1872-9533</eissn><abstract>Thirteen Liassic sedimentary rocks of increasing depth and three petroleums from the Paris Basin were studied for
13C
12C
isotopic compositions and biological markers, including steranes, sterenes, methylphenanthrenes, methylanthracenes, and triaromatic steroids. The isotopic compositions of
n-alkanes from mature sedimentary rocks and petroleums fall in a narrow range (2%.), except for the deepest Hettangian rock and the Trias petroleum, for which the short-chain
n-alkanes are enriched and depleted in
13C, respectively. Most of the molecular parameters increase over the 2000–2500 m depth range, reflecting the transformation of the organic matter at the onset of petroleum generation. In this zone, carbonate content and carbon isotopic composition of carbonates, as well as molecular parameters, are distinct for the Toarcian and Hettangian source rocks and suggest a migration of organic matter from these two formations. Two novel molecular parameters were defined for this task: one using methyltriaromatic steroids from organic extracts; the other using 1-methylphenanthrene and 2-methylanthracene from kerogen pyrolysates. The anomalous high maturity of the Dogger petroleum relative to the maturitydepth trend of the source rocks is used to estimate the minimal vertical distance of migration of the organic matter from the source rock to the reservoir.</abstract><cop>Legacy CDMS</cop><pub>Elsevier Ltd</pub><pmid>11540247</pmid><doi>10.1016/0016-7037(94)90458-8</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-8535-8073</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0016-7037 |
| ispartof | Geochimica et cosmochimica acta, 1994, Vol.58 (1), p.209-221 |
| issn | 0016-7037 1872-9533 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00191892v1 |
| source | MEDLINE; Elsevier ScienceDirect Journals Complete; NASA Technical Reports Server |
| subjects | Alkanes - analysis Alkanes - chemistry Analytical chemistry Anthracenes - analysis Anthracenes - chemistry Calcium Carbonate - analysis Calcium Carbonate - chemistry Carbon - analysis Carbon - chemistry Carbon Isotopes Carbonates - analysis Carbonates - chemistry Chemical Sciences domain_sde.mcg.cpe Earth Sciences Environmental Sciences Exobiology Fossils France Gas Chromatography-Mass Spectrometry Geochemistry Geologic Sediments - analysis Geologic Sediments - chemistry Geophysics Global Changes Paleontology Petroleum - analysis Phenanthrenes - analysis Phenanthrenes - chemistry Sciences of the Universe Space life sciences Stereoisomerism Steroids - analysis Steroids - chemistry |
| title | A molecular and isotopic study of the organic matter from the Paris Basin, France |
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