Dinitrogen Dissociation on an Isolated Surface Tantalum Atom

Both industrial and biochemical ammonia syntheses are thought to rely on the cooperation of multiple metals in breaking the strong triple bond of dinitrogen. Such multimetallic cooperation for dinitrogen cleavage is also the general rule for dinitrogen reductive cleavage with molecular systems and s...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2007-08, Vol.317 (5841), p.1056-1060
Hauptverfasser:	Avenier, P, Taoufik, M, Lesage, A, Solans-Monfort, X, Baudouin, A, de Mallmann, A, Veyre, L, Basset, J.-M, Eisenstein, O, Emsley, L, Quadrelli, E.A
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonia Atoms Catalysis Chemical bonding Chemical bonds Chemical reactions Chemical Sciences Chemistry Exact sciences and technology General and physical chemistry Hydrides Infrared radiation Infrared spectroscopy Metals Nitrogen Nuclear magnetic resonance or physical chemistry Protons Surface chemistry Tantalum Theoretical and Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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