Free radical oxidation (autoxidation) of alkenones and other lipids in cells of Emiliania huxleyi

Autoxidative damages were induced in cells of Emiliania huxleyi by culturing this strain under an atmosphere of air + 0.5% CO 2. Several oxidation products of alkenones, sterols, monounsaturated fatty acids and chlorophyll phytyl side-chain could be detected after NaBH 4 reduction and alkaline hydro...

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Veröffentlicht in:	Phytochemistry (Oxford) 2007-03, Vol.68 (6), p.913-924
Hauptverfasser:	Rontani, Jean-François, Jameson, Ian, Christodoulou, Stéphane, Volkman, John K.
Format:	Artikel
Sprache:	eng
Schlagworte:	algae and seaweeds alkenone Alkenones Alteration of [formula omitted] index autoxidation Biological and medical sciences Borates - chemistry Chemical constitution Emiliania huxleyi Eukaryota - metabolism fatty acid composition Fatty Acids - chemistry Fatty Acids - metabolism Fatty Acids, Unsaturated - chemistry Fatty Acids, Unsaturated - metabolism free radicals Free Radicals - chemistry Free Radicals - metabolism Free-radical oxidation processes Fundamental and applied biological sciences. Psychology Gas Chromatography-Mass Spectrometry Isochrysidales ketones lipids Lipids - chemistry Metabolism Metabolism. Physicochemical requirements Molecular Structure monounsaturated fatty acids Ocean, Atmosphere Oxidation-Reduction Plant physiology and development polyunsaturated fatty acids Sciences of the Universe sterols Sterols - chemistry Sterols - metabolism Sterols, chlorophyll phytyl side-chain Unsaturated fatty acids
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