New Example of a Non-Heme Mononuclear Iron(IV) Oxo Complex. Spectroscopic Data and Oxidation Activity

The green complex S = 1 [(TPEN)FeO]2+ [TPEN = N,N,N‘,N‘-tetrakis(2-pyridylmethyl)ethane-1,2-diamine] has been obtained by treating the [(TPEN)Fe]2+ precursor with meta-chloroperoxybenzoic acid (m-CPBA). This high-valent complex belongs to the emerging family of synthetic models of FeIVO intermediat...

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Veröffentlicht in:	Inorganic chemistry 2005-12, Vol.44 (25), p.9592-9596
Hauptverfasser:	Martinho, Marlène, Banse, Frédéric, Bartoli, Jean-François, Mattioli, Tony A, Battioni, Pierrette, Horner, Olivier, Bourcier, Sophie, Girerd, Jean-Jacques
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Ethylamines - chemistry Inorganic chemistry Iron - chemistry Ligands Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction Oxygen - chemistry Pyridines Pyrimidines - chemistry Sensitivity and Specificity Solutions - chemistry Spectrometry, Mass, Electrospray Ionization - methods Spectroscopy, Fourier Transform Infrared - methods Vibration
Online-Zugang:	Volltext
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