Electrochemical growth of poly(3-dodecylthiophene) into porous silicon: a nanocomposite with tubes or wires?

A derivative of polythiophiene: poly(3-dodecylthiophene) (PT 12) has been used to fill electrochemically a porous silicon matrix. The composite, obtained by this way, should have a high third order nonlinear optical coefficient and good mechanical properties. SEM and TEM micrographs were taken after...

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Veröffentlicht in:Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2003-07, Vol.100 (3), p.259-262
Hauptverfasser: Errien, N., Joubert, P., Chaillou, A., Mahric, C., Godon, C., Louarn, G., Froyer, G.
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container_title Materials science & engineering. B, Solid-state materials for advanced technology
container_volume 100
creator Errien, N.
Joubert, P.
Chaillou, A.
Mahric, C.
Godon, C.
Louarn, G.
Froyer, G.
description A derivative of polythiophiene: poly(3-dodecylthiophene) (PT 12) has been used to fill electrochemically a porous silicon matrix. The composite, obtained by this way, should have a high third order nonlinear optical coefficient and good mechanical properties. SEM and TEM micrographs were taken after matrix dissolution in NaOH. Columns of polymer with the matrix pore shape show up like fingers. In consideration of the homogeneous filling profile of PT 12 measured by EDX and XPS and the low amount of polymer, we are probably dealing with tubes instead of wires.
doi_str_mv 10.1016/S0921-5107(03)00111-9
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identifier ISSN: 0921-5107
ispartof Materials science & engineering. B, Solid-state materials for advanced technology, 2003-07, Vol.100 (3), p.259-262
issn 0921-5107
1873-4944
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source Elsevier ScienceDirect Journals
subjects Infrared spectroscopy
Optics
Physics
Poly(alkylthiophene)
Porous silicon
Transmission microscopy
title Electrochemical growth of poly(3-dodecylthiophene) into porous silicon: a nanocomposite with tubes or wires?
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