Synthesis and characterization of the new delafossite-type oxide CuNi1/3V2/3O2

Whereas neither delafossite-type CuIVIIIO2 nor CuINiIIIO2 exist, the authors have succeeded in preparing the delafossite oxide CuINiII1/3VIII1/3VIV1/3O2, using classical solid-state reaction. The most probable formal oxidation state for nickel is II, while for vanadium it is a mixed state +III/+IV....

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Veröffentlicht in:	Comptes rendus. Chimie 2004, Vol.7 (1), p.29-34
Hauptverfasser:	KHADIJA EL ATAOUI, DOUMERC, Jean-Pierre, AMMAR, Abdelaziz, GRENIER, Jean-Claude, DORDOR, Patrice, POUCHARD, Michel
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chemistry Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...) Exact sciences and technology Inorganic chemistry and origins of life Material chemistry Preparations and properties
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